Rhodium- and ruthenium-catalysed hydrogen isotope exchange

被引：36
|
作者：
Lockley, W. J. S. [1 ]
Hesk, D. [2 ]
机构：
[1] Univ Surrey, Div Chem Sci, Fac Hlth & Med Sci, Guildford GU2 7XH, Surrey, England
[2] Merck Res Labs, Kenilworth, NJ 07033 USA
来源：
JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS | 2010年 / 53卷 / 11-12期
关键词：
rhodium; ruthenium; homogeneous; heterogeneous; deuterium; tritium; exchange; H/D-EXCHANGE; AROMATIC-COMPOUNDS; DEUTERIUM-EXCHANGE; REGIOSELECTIVE DEUTERATION; HETEROGENEOUS RHODIUM; ACTIVATION; HYDROCARBONS; PLATINUM; TRITIUM; ACIDS;
D O I：
10.1002/jlcr.1815
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Metal-catalysed hydrogen isotope exchange has been widely used in the preparation of deuterium- and tritium-labelled compounds. This review details the development and utility of homogeneous and heterogeneous rhodium and ruthenium catalysts for the preparation of deuterium- and tritium-labelled compounds by hydrogen isotope exchange methodology.
引用
收藏
页码：704 / 715
页数：12
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