6,6′-Di-(2"-thiophenol)-2,2′-bipyridine

被引：0

作者：

Huang, Yan ^{[1
]}

Tong, Lianpeng ^{[1
]}

机构：

[1] Guangzhou Univ, Sch Chem & Chem Engn, Higher Educ Mega Ctr, 230 Wai Huan Xi Rd, Guangzhou 510006, Peoples R China

来源：

MOLBANK | 2022年 / 2022卷 / 02期

关键词：

thiophenol; bipyridine; tetradentate ligand; hydrogenase; transition metal; coordination; CRYSTAL-STRUCTURE; HYDROGEN;

D O I：

10.3390/M1355

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This short note describes the synthesis of compound 6,6'-di-(2"-thiophenol)-2,2'-bipyridine from its methyl phenyl sulfane precursor via deprotection of the methyl groups. The product as well as the intermediate in the synthetic route have been characterized by UV-Vis spectroscopy, H-1- and C-13-NMR spectroscopy, FT-IR spectroscopy, and HR-MS analysis. This work presents a rare example of tetradentate chelators that bears pyridyl backbones and thiophenol donors for the coordination with 3d-transition metal cations.

引用

页数：5

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