Redox-active Schiff base ligands

被引：11
|
作者：
Hall, CD [1 ]
Sachsinger, N [1 ]
Nyburg, SC [1 ]
Steed, JW [1 ]
机构：
[1] Univ London Kings Coll, Dept Chem, London WC2R 2LS, England
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 561卷 / 1-2期
基金：
英国工程与自然科学研究理事会;
关键词：
Schiff base; ferrocene; Ag+-complex; Cu+-complex; X-ray crystallography;
D O I：
10.1016/S0022-328X(98)00530-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The syntheses and characterisation of two redox-active Schiff base ligands containing ferrocene are described, and their complex formation with Cu+ and Ag+ examined by UV/vis and H-1-, C-13-NMR spectroscopy, cyclic voltammetry and X-ray crystallography. Crystals of the complex formed between bis-(3-ethylenedi-imino-4-methoxyphenyl)ferrocene and AgBF4 belong to the highly unusual cubic system and spontaneous resolution of the helical, tetrahedral complex is observed. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：209 / 219
页数：11
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