Acetonitrilebis(2-methyl-1,10-phenanthroline)copper(II) tetrafluoridoborate

被引：1
|
作者：
Watton, Stephen P. [1 ]
机构：
[1] Cent Connecticut State Univ, Dept Chem & Biochem, New Britain, CT 06050 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
D O I：
10.1107/S1600536810038845
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu(CH3CN)(C13H10N2)(2)](BF4)(2), the fivefold-coordinate Cu-II atom is located on a twofold rotation axis, imposing twofold symmetry to the complete cation. The structure exhibits disorder of the anion, which was successfully refined using a two-site model with 0.810 (3):0.190 (3) occupancy. The methyl group of the acetonitrile ligand is likewise disordered, here about the twofold rotation axis in a 1:1 ratio.
引用
收藏
页码：M1359 / U230
页数：10
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