Synthesis, curing of hydroxyl-terminated liquid fluoroelastomer: thermal, chemical resistant and mechanical properties

被引:6
|
作者
Li, N. [1 ]
Wu, J. J. [2 ]
Wang, Y. Q. [2 ]
Wu, J. H. [2 ]
Zhang, J. J. [3 ]
Huo, J. Z. [3 ]
Bai, Y. P. [1 ]
机构
[1] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Heilongjiang, Peoples R China
[2] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China
[3] FoShan NanHai Gotop Packaging Mat Co Ltd, Foshan 528225, Peoples R China
关键词
FLUORINATED POLYURETHANES; MORPHOLOGY;
D O I
10.1088/1757-899X/213/1/012029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel hydroxyl-terminated liquid fluoroelastomer (HTLF) was synthesized; FT-IR, GPC and H-1-NMR result show that HTLF was synthesized successfully. Then HTLF was cured with HDI trimer, the structure of cured product was characterized by FT-IR. Compared with traditional solid fluorine elastomer, Cured HTLF has higher char yield and faster thermal decomposition rate. It ascribed to the introduction of ring structure the cross-link structure formed in the curing process. The study of chemical resistant properties and tensile strength of cured fluoroelastomer film suggested that Cured HTLF was provided with similar mmechanical properties, chemical resistant property than solid fluorine elastomer.
引用
收藏
页数:8
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