Chiral molybdenum(0) and tungsten(0) carbonyl diimine complexes

被引：5

作者：

Karakus, Mehmet ^{[1
]}

Davulga, Gulnihal ^{[1
]}

Gomez-Ruiz, Santiago ^{[2
]}

Tschirschwitz, Steffen ^{[2
]}

Hey-Hawkins, Evamarie ^{[2
]}

机构：

[1] Pamukkale Univ, Fac Arts & Sci, Dept Chem, TR-20017 Kinikli, Denizli, Turkey

[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

POLYHEDRON | 2009年 / 28卷 / 01期

关键词：

Chiral diimine ligand; Molybdenum; Tungsten; Carbonyl complexes; SCHIFF-BASE LIGANDS; TETRACARBONYL COMPLEXES; CRYSTAL-STRUCTURES; ACID; ALKYLATIONS; CATALYSTS; ESTERS;

D O I：

10.1016/j.poly.2008.10.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral diimine ligand C5H4N-2-C(C6H5)=N{(1S,2S)-C5H8-2-OCH2C6H5)} (1) was prepared via the reaction of 2-benzoyl pyridine and (1S,2S)-(+)-2-benzyloxycyclopentylamine. 1 (=L) reacts with M(CO)(6) in toluene to give the respective metal(0) complexes [M(CO)(4)(L-kappa N,N')] (M = Mo (2) and W(3)). 1-3 were fully characterized by elemental analyses, 1R, multinuclear NMR spectroscopy and MS. The complexes 2 and 3 are isostructural and crystallize in the chiral hexagonal space group P3(1) with three molecules in the unit cell. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：91 / 94

页数：4

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