Measurement of Vapor-liquid Equilibria (VLE) for the Ternary, Propane plus Dimethyl Ether plus Butane, and the Three Constituent Binaries, and Predicted Values by the Benedict-Webb-Rubin (BWR) Equation of State: Measurement and Prediction of Thermophysical Properties for Dimethyl Ether with Liquefied Petroleum Gas Components (Part 2)

被引:3
|
作者
Tsuji, Tomoya [1 ]
Hoshina, Taka-aki [2 ]
机构
[1] Univ Teknol Malaysia, Malaysia Japan Int Inst Technol, Dept Chem & Environm Engn, Jalan Sultan Yahya Petra, Kuala Lumpur 54100, Malaysia
[2] Nihon Univ, Coll Ind Technol, Dept Appl Mol Chem, 1-2-1 Izumicho, Narashino, Chiba 2758575, Japan
关键词
Dimethyl ether; Propane; Butane; Vapor-liquid equilibrium; Saturated liquid density; BWR equation of state; N-BUTANE; PRESSURE MEASUREMENTS; PHASE-EQUILIBRIA; CARBON-DIOXIDE; SYSTEMS; SOLUBILITY; DME; TEMPERATURES; DENSITIES;
D O I
10.1627/jpi.63.172
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The vapor-liquid equilibrium (VLE) and the saturated liquid density were measured for three binaries, propane + dimethyl ether (DME), DME + butane, and propane + butane, and the ternary, propane + DME + butane, at 313.15 +/- 0.03 K. The apparatus was based on a recirculation method and incorporated an oscillation U-tube densimeter. Deviation of the saturated vapor pressure for pure propane, DME and butane were 0.556, 0.525, and 6.210 %, respectively, and that for the saturated liquid density for DME was 0.552 %, compared with the reported values. The experimental binary VLE data for propane + DME, DME + butane and propane + butane, agreed with reported values. The data were correlated with the prediction of the Benedict-Webb-Rubin (BWR) equation of state. The constants in the BWR equation for DME were determined in our previous research, and those for propane and butane were obtained from the literature. The correlation showed a good reproducibility. The averaged absolute deviations (AADs) for the mole fractions in the liquid and vapor phases were 2.156 % and 1.687 %, respectively, and for the saturated liquid density was than 1.490 %. The ternary VLE and the saturated liquid density was measured at 0.8830 MPa and 313.15 K. The VLE and the saturated liquid density were estimated by the BWR equation using only the binary parameters. The AADs for the mole fractions in the liquid and vapor phases were 2.905 % and 2.110 %, and that for the saturated liquid density was 1.432 %.
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页码:172 / 183
页数:12
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