A three-dimensional hydrogen-bonded network of diaquabis(2,5-di-3-pyridyl-1,3,4-oxadiazole)dithiocyanatoiron(II)

被引：6
|
作者：
Zhao, XJ [1 ]
Guo, JH [1 ]
Du, M [1 ]
机构：
[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805011268
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecular structure of the neutral mononuclear complex [Fe(NCS)(2)(3-bpo)(2)(H2O)(2)], in which 3-bpo denotes 2,5-di-3-pyridyl- 1,3,4-oxadiazole (C12H8N4O), is centrosymmetric, with Fe-II located on an inversion center. This complex is octahedral, and the Fe-II atom is trans coordinated by two monodentate NSC- ligands, two monodentate 3-bpo ligands and two water molecules. Each complex is linked to four others, forming a (011) sheet, by O - H center dot center dot center dot N hydrogen bonding. Weak C - H center dot center dot center dot S interactions link each ( 011) sheet to the two adjacent sheets, hence forming a three-dimensional array. There is also some slipped pi stacking within each sheet.
引用
收藏
页码：M913 / M915
页数：3
相关论文
共 50 条
  • [1] Diaquabis(2,5-di-3-pyridyl-1,3,4-oxadiazole)dithiocyanatomanganese(II):: a three-dimensional supramolecular network formed through O-H ••• N and C-H ••• S interactions
    Du, M
    Jiang, XJ
    Zhao, XJ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : M485 - M487
  • [2] Hydrogen-bonded sheets in the 1:1 cocrystal of biphenyl-4,4'-dicarboxylic acid with 2,5-di-pyridyl)-1,3,4-oxadiazole
    Du, M
    You, YP
    Zhang, ZH
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2006, 62 : O33 - O35
  • [3] Hydrogen-bonded sheets in the 1:1 cocrystal of biphenyl-4,4′-dicarboxylic acid with 2,5-di-4-pyridyl-1,3,4-oxadiazole
    Du, Miao
    You, Yan-Ping
    Zhang, Zhi-Hui
    Acta Crystallogr Sect C Cryst Struct Commun, 1 (o33-o35):
  • [4] 1:1 Cocrystal of 2,5-di-4-pyridyl-1,3,4-oxadiazole and hydroquinone
    Wang, YT
    Tang, GM
    Qin, DW
    Duan, HD
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O45 - O46
  • [5] 2,5-Di-p-tolyl-1,3,4-oxadiazole
    Reck, G
    Orgzall, I
    Schulz, B
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1135 - O1136
  • [6] Cocrystal of 2,5-di-4-pyridyl-1,3,4-oxadiazole and malonic acid(1/1)
    Wang, YT
    Tang, GM
    Qin, DW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O3979 - O3980
  • [7] Bis( 2,5-di-4-pyridyl-1,3,4-oxadiazole)silver(I) nitrate monohydrate
    Zhang, Zhi-Hui
    Li, Cheng-Peng
    Tian, Yi-Ling
    Guo, Ya-Mei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M3044 - U1669
  • [8] Bis(μ-2,5-di-3-pyridyl-1,3,4-oxadiazole-κ2 N2:N5)disilver(I) bis(trifluoromethanesulfonate)
    Li, J
    Ma, JP
    Xia, JB
    Huang, RQ
    Dong, YB
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M247 - M248
  • [9] Bis[aqua(2,5-bis(4-pyridyl)-1,3,4-oxadiazole)thiocyanate] cadmium(II): A three-dimensional framework built from hydrogen bonds and π-π stacking interactions
    Miao Du
    He Liu
    Xian-He Bu
    Journal of Chemical Crystallography, 2002, 32 : 57 - 61
  • [10] Bis[aqua(2,5-bis(4-pyridyl)-1,3,4-oxadiazole)thiocyanate] cadmium(II):: A three-dimensional framework built from hydrogen bonds and π-π stacking interactions
    Du, M
    Liu, H
    Bu, XH
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2002, 32 (3-4) : 57 - 61
12345