Reaction of N-sulfinyltrifluoromethanesulfonamide with triphenylphosphine and triphenylphosphine oxide

被引：0
|
作者：
Tolstikova, L. L. [1 ]
Bel'skikh, A. V. [1 ]
Shainyan, B. A. [1 ]
机构：
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 06期
关键词：
Triphenylphosphine; Triphenyl; Phosphine Oxide; Triphenylphosphine Oxide; Methanesulfonamide;
D O I：
10.1134/S107036321006023X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of N-sulfinyltrifluoromethanesulfonamide with triphenylphosphine and triphenylphosphine oxide or of trifluoromethanesulfonamide with dichloro(triphenyl)phosphorane leads to trifluoro-N-(triphenyl-lambda(5)-phosphanylidene)methanesulfonamide, which is hydrolyzed to trifluoromethanesulfonamide and triphenylphosphine oxide via the intermediate trifluoro-N-[hydroxy(triphenyl)phosphoranyl]methanesulfonamide.
引用
收藏
页码：1189 / 1192
页数：4
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