Retention of anions on silica-based metalloporphyrin stationary phases

被引：0
|
作者：
Biesaga, M [1 ]
Stolarczyk, E [1 ]
Pyrzynska, K [1 ]
Trojanowicz, M [1 ]
机构：
[1] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland
来源：
ANALYTICAL SCIENCES | 2002年 / 18卷 / 02期
关键词：
D O I：
10.2116/analsci.18.151
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The silica-based Fe(III)-protoporphyrin and Zn-tetraphenylporphyrin stationary phases were examined for the HPLC separation of anions. The retention of nine common inorganic anions as well as benzoate anion (BA) and its hydroxy analogues (HBA) was examined using tartrate, acetate, and succinate eluents. The retention factors of inorganic anions on the FeProP stationary phase were in the order Cl- < NO3- < ClO4- < I- < SCN- and for organic anions benzoate < p-hydroxybenzoate < m-hydoxybenzoate < o-hydroxybenzoate. The retention factors of organic anions examined for a ZnTPP column were in the order p-HBA < m-HBA < BA < o-HBA.
引用
收藏
页码：151 / 154
页数：4
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