Rhodium-Catalyzed Asymmetric Synthesis of Spirosilabifluorene Derivatives

被引：204

作者：

Kuninobu, Yoichiro ^{[1
]}

Yamauchi, Kanae ^{[1
]}

Tamura, Naoya ^{[1
]}

Seiki, Takayuki ^{[1
]}

Takai, Kazuhiko ^{[1
]}

机构：

[1] Okayama Univ, Grad Sch Nat Sci & Technol, Div Chem & Biotechnol, Kita Ku, Okayama 7008530, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 05期

关键词：

asymmetric synthesis; C?H activation; rhodium; silicon; synthetic methods; ENANTIOSELECTIVE SYNTHESIS; 2+2+2 CYCLOADDITION; SILAFLUORENES; CONSTRUCTION; CYCLIZATION;

D O I：

10.1002/anie.201207723

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Si goes chiral: Treatment of a bis(biphenyl)silane with a catalytic amount of a rhodium complex gave a spirosilabifluorene bearing a quaternary silicon atom. By using a rhodium catalyst with a chiral phosphine ligand (see scheme), asymmetric dehydrogenative cyclization proceeded to give chiral derivatives in good yields and enantioselectivities. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1520 / 1522

页数：3

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