Determination of Trichloroacetic Acid (TCAA) Using CdO Nanoparticles Modified Carbon Paste Electrode

被引:11
|
作者
Najafi, Mostafa [1 ]
Darabi, Salman [1 ]
Tadjarodi, Azadeh [2 ]
Imani, Mina [2 ]
机构
[1] Imam Hossein Univ, Fac Sci, Dept Chem, Tehran 16597, Iran
[2] Iran Univ Sci & Technol, Dept Chem, Res Lab Inorgan Mat Synth, Tehran 1684613114, Iran
关键词
Cadmium oxide; Nanoparticles; Carbon paste electrode; Electrocatalysis; Trichloroacetic acid; LPG SENSING PROPERTIES; THIN-FILMS; CADMIUM-OXIDE; OPTICAL-PROPERTIES; NANOCRYSTALS; NANOTUBES; ELECTROCHEMISTRY; BIOSENSOR; PRECURSOR; SURFACES;
D O I
10.1002/elan.201200462
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this paper, the electrochemical behavior of a carbon paste electrode modified with CdO nanoparticles as a potential electrocatalyst for the reduction of trichloroacetic acid (TCAA) was investigated using cyclic voltammetry and double-potential step chronoamperometry. The modified electrode showed a great enhancement in cathodic peak current with respect to reduction of TCAA in acidic aqueous solution. Using this increment, a quantitative method was developed for the determination of TCAA in aqueous solution. The detection limit and linear dynamic range of TCAA are 2.3x106M and 2.3x1043x106M, respectively.
引用
收藏
页码:487 / 492
页数:6
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