Catalytic performance of silver ion-exchanged saponite for the selective reduction of nitrogen monoxide in the presence of excess oxygen

被引:23
|
作者
Sato, K
Fujimoto, T
Kanai, S
Kintaichi, Y
Inaba, M
Haneda, M
Hamada, H
机构
[1] NATL INST MAT & CHEM RES,HIGASHI KU,TSUKUBA,IBARAKI 305,JAPAN
[2] COSMO RES INST,SATTE,SAITAMA 34001,JAPAN
关键词
nitrogen monoxide; selective reduction; Ag-saponite; water vapor; hydrocarbons; oxygenated hydrocarbons;
D O I
10.1016/S0926-3373(96)00091-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The catalytic activity of ion-exchanged saponites for NO reduction with hydrocarbons in the presence of oxygen was investigated. Silver ion-exchanged saponite (Ag-saponite) showed excellent catalytic activity for NO reduction with propene. The highest activity was obtained for Ag-saponite with a silver loading of 7-8 wt%, on which the addition of water vapor to the feed gas promoted NO reduction at temperatures below 400 degrees C. 2-Propanol and acetone served as more efficient reducing agents in the presence of water vapor.
引用
收藏
页码:27 / 33
页数:7
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