Rates of C-S bond cleavage in tert-alkyl phenyl sulfide radical cations

被引：30
|
作者：
Baciocchi, E
Del Giacco, T
Gerini, MF
Lanzalunga, O
机构：
[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
[2] CNR, IMC, Sez Meccanismi Reaz, I-00185 Rome, Italy
[3] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
[4] Univ Perugia, CEMIN, I-06123 Perugia, Italy
来源：
ORGANIC LETTERS | 2006年 / 8卷 / 04期
关键词：
D O I：
10.1021/ol052834y
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Radical cations of tert-alkyl phenyl sulfides 1-4 have been generated photochemically in MeCN in the presence of the N-methoxyphenanthridinium cation (MeOP+), and the rates of C-S bond cleavage have been determined by laser flash photolysis.
引用
收藏
页码：641 / 644
页数：4
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