Adsorption properties and inhibition of mild steel corrosion in sulphuric acid solution by ketoconazole: Experimental and theoretical investigation

被引：392

作者：

Obot, I. B. ^{[1
]}

Obi-Egbedi, N. O. ^{[2
]}

机构：

[1] Univ Uyo, Fac Sci, Dept Chem, Uyo, Akwa Ibom State, Nigeria

[2] Univ Ibadan, Dept Chem, Ibadan, Nigeria

来源：

CORROSION SCIENCE | 2010年 / 52卷 / 01期

关键词：

Ketoconazole; Mild steel; Corrosion inhibition; Quantum chemistry; Sulphuric acid; METAL-LIGAND INTERACTION; ABSOLUTE ELECTRONEGATIVITY; EXUDATE GUM; HALIDE-IONS; ALUMINUM; DERIVATIVES; MECHANISM; DYE; 2,3-DIAMINONAPHTHALENE; BENZIMIDAZOLE;

D O I：

10.1016/j.corsci.2009.09.002

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Ketoconazole (KCZ) has been evaluated as a corrosion inhibitor for mild steel in aerated 0.1 M H2SO4 by gravimetric method. The effect of KCZ on the corrosion rate was determined at various temperatures and concentrations. The inhibition efficiency increases with increase in inhibitor concentration but decrease with rise in temperature. Adsorption followed the Langmuir isotherm with negative values of Delta G(ads)degrees, suggesting a stable and a spontaneous inhibition process. Quantum chemical approach was further used to calculate some electronic properties of the molecule in order to ascertain any correlation between the inhibitive effect and molecular structure of ketoconazole. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：198 / 204

页数：7

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