Improving chemical recycling rate by reclaiming polyurethane elastomer from polyurethane foam

被引:26
|
作者
Watando, Hiroko [1 ]
Saya, Shioko [1 ]
Fukaya, Taro [1 ]
Fujieda, Shinetsu [1 ]
Yamamoto, Masaaki [1 ]
机构
[1] Toshiba Co Ltd, Ctr Corp Res & Dev, Saiwai Ku, Yokohama, Kanagawa 2128582, Japan
关键词
polyurethane; chemical recycling; foam; elastomer; reclamation;
D O I
10.1016/j.polymdegradstab.2006.05.017
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Flexible polyurethane foam was decomposed into a polyol mixture by an extruder with diethanolamine (DEA) as a decomposing agent. The resulting decomposed product could be used as an alternative virgin polyol in reclaiming polyurethane. In the case of reclaiming elastomer by using the decomposed product without any purification, virgin polyol could be alternated by the decomposed product up to 80%. It is a great improvement compared with the reclamation to foam, whose percentage was maximum 5 %. Furthermore, the percentage could be improved up to 100% by purifying the decomposed product. We have found that physical properties of reclaimed polyurethane elastomer, such as tensile strength, hardness, and elongation, can be regulated by the ratio of unrefined/refined polyol. Whereas the tensile strength and the hardness increased as the content increased, the elongation decreased. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3354 / 3359
页数:6
相关论文
共 50 条
  • [1] Chemical recycling of mixed polyurethane foam stream recovered from shredder residue into polyurethane polyols
    Sendijarevic, Vahid
    [J]. JOURNAL OF CELLULAR PLASTICS, 2007, 43 (01) : 31 - 46
  • [2] Chemical Recycling of Polyurethane Foam Waste Via Glycolysis
    Aguado, Alicia
    Martinez, Lidia
    Moral, Alberto
    Fermoso, Jose
    Irusta, Ruben
    [J]. ICHEAP-10: 10TH INTERNATIONAL CONFERENCE ON CHEMICAL AND PROCESS ENGINEERING, PTS 1-3, 2011, 24 : 1069 - 1074
  • [3] RECYCLING OF POLYURETHANE AND POLYISOCYANURATE FOAM
    ULRICH, H
    ODINAK, A
    TUCKER, B
    SAYIGH, AAR
    [J]. POLYMER ENGINEERING AND SCIENCE, 1978, 18 (11): : 844 - 848
  • [4] RECYCLING OF POLYURETHANE AND ISOCYANURATE FOAM
    ULRICH, H
    [J]. ADVANCES IN URETHANE SCIENCE AND TECHNOLOGY, 1978, 5 : 49 - 57
  • [5] RECYCLING OF MICROCELLULAR POLYURETHANE ELASTOMER WASTE
    MODESTI, M
    SIMIONI, F
    RIENZI, SA
    [J]. JOURNAL OF ELASTOMERS AND PLASTICS, 1992, 24 (04): : 288 - 305
  • [6] Chemical recycling for polyurethane
    Saya, S
    Thai, CM
    [J]. Materials in the Automotive Industry, 2001, : 31 - 39
  • [7] Reheating decomposition process as chemical recycling for rigid polyurethane foam
    Fukaya, Taro
    Watando, Hiroko
    Fujieda, Shinetsu
    Saya, Shioko
    Thai, Cao Minh
    Yamamoto, Masaaki
    [J]. POLYMER DEGRADATION AND STABILITY, 2006, 91 (11) : 2549 - 2553
  • [8] Reviewing the thermo-chemical recycling of waste polyurethane foam
    Deng, Yimin
    Dewil, Raf
    Appels, Lise
    Ansart, Renaud
    Baeyens, Jan
    Kang, Qian
    [J]. JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2021, 278
  • [9] Continuous process for recycling of polyurethane foam
    Ghose, S
    Isayev, AI
    [J]. JOURNAL OF CELLULAR PLASTICS, 2004, 40 (03) : 167 - 189
  • [10] Chemical Recycling of Polyurethane Foam Waste with Glycolysis by Using Zeolite Catalysts
    Dinc, Metin
    Yildiz, Meltem
    Aytac, Ayse
    [J]. KGK Kautschuk Gummi Kunststoffe, 2020, 73 (7-8): : 31 - 35