A metal-free polymeric photocatalyst for hydrogen production from water under visible light

被引：3935
|
作者：
Wang, Xinchen [1 ,2 ]
Maeda, Kazuhiko [3 ]
Thomas, Arne [1 ]
Takanabe, Kazuhiro [3 ]
Xin, Gang [3 ]
Carlsson, Johan M. [4 ]
Domen, Kazunari [3 ]
Antonietti, Markus [1 ]
机构：
[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany
[2] Fuzhou Univ, State Key Lab Breeding Base Photocatalysis, Res Inst Photocatalysis, Fuzhou 350002, Peoples R China
[3] Univ Tokyo, Sch Engn, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
[4] Max Planck Soc, Fritz Haber Inst, Theory Dept, D-14195 Berlin, Germany
来源：
NATURE MATERIALS | 2009年 / 8卷 / 01期
基金：
日本学术振兴会;
关键词：
SOLID-SOLUTION; H-2; EVOLUTION; IRRADIATION; CATALYSTS; OXYNITRIDE; REDUCTION; OXIDATION; CLEAVAGE; CLUSTER; OXYGEN;
D O I：
10.1038/NMAT2317
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The production of hydrogen from water using a catalyst and solar energy is an ideal future energy source, independent of fossil reserves. For an economical use of water and solar energy, catalysts that are sufficiently efficient, stable, inexpensive and capable of harvesting light are required. Here, we show that an abundant material, polymeric carbon nitride, can produce hydrogen from water under visible-light irradiation in the presence of a sacrificial donor. Contrary to other conducting polymer semiconductors, carbon nitride is chemically and thermally stable and does not rely on complicated device manufacturing. The results represent an important first step towards photosynthesis in general where artificial conjugated polymer semiconductors can be used as energy transducers.
引用
收藏
页码：76 / 80
页数：5
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