ESR study of reduced vanadium-titanium oxide catalysts

被引：6
|
作者：
Altynnikov, AA [1 ]
Zenkovets, GA [1 ]
Anufrienko, VF [1 ]
机构：
[1] Boreskov Inst Catalysis, Novosibirsk 630090, Russia
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1999年 / 67卷 / 02期
关键词：
vanadium-titanium oxide catalyst; reduction with hydrogen; ESR;
D O I：
10.1007/BF02475771
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Reduction of vanadium-titanium oxide catalysts with hydrogen in the temperature range of 150-450 degrees C results in the increase of the content of V4+ ions in substitution positions of TiO2 with the anatase structure. The temperature increase up to 250 degrees C results in the growth of the spectral intensity of V4+ associates in substitution positions of anatase. At higher treatment temperatures their intensity decreases due to the formation of VO2 fragments in anatase. At 400 degrees C and higher temperatures a solid solution of V4+ ions in rutile is formed.
引用
收藏
页码：273 / 279
页数：7
相关论文
共 50 条
  • [1] ESR study of reduced vanadium-titanium oxide catalysts
    A. A. Altynnikov
    G. A. Zenkovets
    V. F. Anufrienko
    Reaction Kinetics and Catalysis Letters, 1999, 67 : 273 - 279
  • [2] Structure peculiarities of reduced vanadium-titanium oxide catalysts
    Zenkovets, GA
    Kryukova, GN
    Tsybulya, SV
    Anufrienko, VF
    Gavrilov, VY
    KINETICS AND CATALYSIS, 2001, 42 (01) : 132 - 137
  • [3] VANADIUM-TITANIUM OXIDE AEROGEL CATALYSTS
    WILLEY, RJ
    WANG, CT
    PERI, JB
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 186 : 408 - 414
  • [4] Vanadium-titanium oxide aerogel catalysts
    J Non Cryst Solids, (408):
  • [5] VANADIUM-TITANIUM OXIDE CATALYSTS FOR OXIDATION OF BUTENE
    SLINKARD, WE
    DEGROOT, PB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 179 (MAR): : 76 - COLL
  • [6] LASER SYNTHESIS OF VANADIUM-TITANIUM OXIDE CATALYSTS
    MUSCI, M
    NOTARO, M
    CURCIO, F
    CASALE, C
    DEMICHELE, G
    JOURNAL OF MATERIALS RESEARCH, 1992, 7 (10) : 2846 - 2852
  • [7] Catalytic oxidation of durene into pyrromellitic dianhydride on vanadium-titanium oxide catalysts
    Kutepov, BI
    Arslanov, FG
    Bal'zhinimaev, BS
    Pinaeva, LG
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2000, 73 (07) : 1181 - 1185
  • [8] FTIR study of the role of surface complexes in a transformation of picoline isomers on vanadium-titanium oxide catalysts
    Chesalov, Yuriy A.
    Andrushkevich, Tamara V.
    Baltakhinov, Vladimir P.
    VIBRATIONAL SPECTROSCOPY, 2016, 83 : 138 - 150
  • [9] Apparent Absorption Spectra of Silica Supported Vanadium-Titanium Oxide Catalysts: Experimental Study and Modeling
    Klokishner, S.
    Reu, O.
    Tzolova-Mueller, G.
    Schloegl, R.
    Trunschke, A.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (26): : 14677 - 14691
  • [10] Topology of silica supported vanadium-titanium oxide catalysts for oxidative dehydrogenation of propane
    Hamilton, Neil
    Wolfram, Till
    Mueller, Genka Tzolova
    Haevecker, Michael
    Kroehnert, Jutta
    Carrero, Carlos
    Schomaecker, Reinhard
    Trunschke, Annette
    Schloegl, Robert
    CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (07) : 1346 - 1359
12345