Ring-opening copolymerization of (R)-β-butyrolactone with macrolide:: A new series of poly(hydroxyalkanoate)s

被引：24

作者：

Hori, Y ^{[1
]}

Hongo, H ^{[1
]}

Hagiwara, T ^{[1
]}

机构：

[1] Takasago Int Corp, Cent Res Lab, Hiratsuka, Kanagawa 2540073, Japan

来源：

MACROMOLECULES | 1999年 / 32卷 / 10期

关键词：

D O I：

10.1021/ma981846e

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The ring-opening copolymerization of (R)-β-butyrolactone (R)-BL) with several lactones was attempted using distannoxane complexes as new catalysts. A new series of poly(hydroxyalkanoate)s comprised of (R)-3-hydroxybutanoate was obtained. The elongation-to-breaks of P[(R)-3HB-co-10% 15-PD] and P[(R)-3HB-co-10% 16-HD] were unexpectedly and extremely large.

引用

页码：3537 / 3539

页数：3

共 50 条

[1] Functional Syndiotactic Poly(β-hydroxyalkanoate)s via Stereoselective Ring-Opening Copolymerization of rac-β-Butyrolactone and rac-Allyl-β-Butyrolactone
Ajellal, Noureddine
Thomas, Christophe M.
Carpentier, Jean-Francois
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (12) : 3177 - 3189
[2] Ring-opening copolymerization of (R)-beta-butyrolactone with cyclic carbonates: New biodegradable poly(ester carbonate)s
Hori, Y
Gonda, Y
Takahashi, Y
Hagiwara, T
[J]. MACROMOLECULES, 1996, 29 (02) : 804 - 806
[3] From Anionic Ring-Opening Polymerization of β-Butyrolactone to Biodegradable Poly(hydroxyalkanoate)s: Our Contributions in This Field
Adamus, Grazyna
Dominski, Adrian
Kowalczuk, Marek
Kurcok, Piotr
Radecka, Iza
[J]. POLYMERS, 2021, 13 (24)
[4] Ring-opening copolymerization of (R,S)-β-butyrolactone and ε-caprolactone using sodium hydride as initiator
Monsalve, M.
Contreras, J. M.
Laredo, E.
Lopez-Carrasquero, F.
[J]. EXPRESS POLYMER LETTERS, 2010, 4 (07): : 431 - 441
[5] Immortal ring-opening polymerization of β-butyrolactone with zinc catalysts: Catalytic approach to poly(3-hydroxyalkanoate)
Guillaume, Clemence
Carpentier, Jean-Francois
Guillaume, Sophie M.
[J]. POLYMER, 2009, 50 (25) : 5909 - 5917
[6] New way of anionic ring-opening copolymerization of β-butyrolactone and ε-caprolactone: determination of the reaction course
Grobelny, Zbigniew
Jurek-Suliga, Justyna
Golba, Sylwia
[J]. JOURNAL OF POLYMER RESEARCH, 2020, 27 (12)
[7] New way of anionic ring-opening copolymerization of β-butyrolactone and ε-caprolactone: determination of the reaction course
Zbigniew Grobelny
Justyna Jurek-Suliga
Sylwia Golba
[J]. Journal of Polymer Research, 2020, 27
[8] RING-OPENING COPOLYMERIZATION OF (R)-BETA-BUTYROLACTONE WITH (R)-3-METHYL-4-OXA-6-HEXANOLIDE - A NEW BIODEGRADABLE POLY(ESTER-ETHER)
HORI, Y
YAMAGUCHI, A
[J]. MACROMOLECULES, 1995, 28 (01) : 406 - 408
[9] Chemosynthesis of bioresorbable poly(γ-butyrolactone) by ring-opening polymerisation:: a review
Moore, T
Adhikari, R
Gunatillake, P
[J]. BIOMATERIALS, 2005, 26 (18) : 3771 - 3782
[10] Structure and morphology of poly(β-hydroxybutyrate) synthesized by ring-opening polymerization of racemic (R,S)-β-butyrolactone with distannoxane derivatives
Arcana, M
Giani-Beaune, O
Schue, F
Amass, W
Amass, A
[J]. POLYMER INTERNATIONAL, 2000, 49 (11) : 1348 - 1355

← 1 2 3 4 5 →