Effect of Active Metal Loading on Catalytic Activity of V2O5/TiO2 Catalysts

被引:0
|
作者
Jang, Younghee [1 ]
Kim, Sung Chul [2 ]
Kim, Sung Su [2 ]
机构
[1] Kyonggi Univ, Dept Environm Energy Engn, Grad Sch, Suwon 16227, South Korea
[2] Kyonggi Univ, Dept Environm Energy Engn, Suwon 16227, South Korea
来源
APPLIED CHEMISTRY FOR ENGINEERING | 2022年 / 33卷 / 05期
关键词
H2S; Catalytic oxidation; Odor; Vanadium; SELECTIVE OXIDATION; ELEMENTAL SULFUR; H2S; BIOGAS;
D O I
10.14478/ace.2022.1076
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this study, the activity test and characterization were performed to evaluate the hydrogen sulfide removal characteristics using a V/TiO2 catalyst at room temperature. The optimal vanadium loading was 10 wt%, and the durability was greater than 60 minutes at 60-80% relative humidity. The Brunauer-Emmett-Teller (BET) surface area and raman spectroscopy results confirmed that the structure of the vanadium site exposed to the surface was a dominant factor in catalyst activity. From Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS) and X-ray crystallography (XRD) analyses, it was found that sulfur can be accumulated on the catalyst surface, which results in a decrease in durability under catalytic activity tests. Therefore, it is judged that a combined process of catalytic oxidation and regeneration is needed.
引用
收藏
页码:482 / 487
页数:6
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