Polarizability of a pair of hydrogen molecules

被引：0
|
作者：
Ulivi, L
Zoppi, M
机构：
[1] Istituto di Elettronica Quantistica, CNR, Firenze, 50127
来源：
MOLECULAR PHYSICS | 1997年 / 90卷 / 06期
关键词：
D O I：
10.1080/002689797171968
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The interaction polarizability of two hydrogen molecules is calculated by the ab initio method of Bounds, D. G., 1976, Molec. Phys., 38, 2099 in terms of spherical coordinates. A good representation is obtained for the anisotropy, using six coefficients in the expansion, while no satisfactory results are obtained for the isotropic part. A comparison with experimental collision-induced light scattering spectral moments and with the recently measured intensity of the double rotational transition is made, and the results discussed in detail.
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页码：971 / 978
页数：8
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