In situ Seamless Magnetic Measurements for Solid-State Electrochemical Processes in Prussian Blue Analogues

被引：23
|
作者：
Yamada, Tetsuya [1 ,2 ,3 ]
Morita, Kantaro [1 ,2 ]
Wang, Heng [1 ,2 ]
Kume, Keita [1 ,2 ]
Yoshikawa, Hirofumi [1 ,2 ]
Awaga, Kunio [1 ,2 ,3 ]
机构：
[1] Nagoya Univ, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Res Ctr Mat Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] JST, CREST, Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 24期
关键词：
electrochemistry; lithium batteries; magnetic properties; Prussian blue analogues; redox chemistry; MOLECULAR-CLUSTER BATTERIES; X-RAY-ABSORPTION; ORDERING TEMPERATURE; POLE INVERSION; AIR BATTERIES; ELECTROLYTE; TRANSITION; MOBILITY;
D O I：
10.1002/anie.201301084
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Seamless observation: Magnetic measurements in a solid-state electrochemical environment have been developed and applied to a mixed-valent chromium Prussian blue analogue (PBA) ferrimagnet. Battery cells containing PBA as a cathode active material were inserted into a SQUID and the PBA reduction during battery discharge was controlled. Magnetic changes were revealed that can be understood by the redox-induced spin changes of the Cr ions. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：6238 / 6241
页数：4
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