Anion-dependent construction of two hexanuclear 3d-4f complexes with a flexible Schiff base ligand

被引：62

作者：

Yang, Xiaoping ^{[1
]}

Chan, Christopher ^{[1
]}

Lam, Daniel ^{[1
]}

Schipper, Desmond ^{[1
]}

Stanley, Julie M. ^{[1
]}

Chen, Xiaoyan ^{[1
]}

Jones, Richard A. ^{[1
]}

Holliday, Bradley J. ^{[1
]}

Wong, Wai-Kwok ^{[2
,3
]}

Chen, Shengchun ^{[1
]}

Chen, Qun ^{[4
]}

机构：

[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

[3] Hong Kong Baptist Univ, Ctr Adv Luminescence Mat, Kowloon Tong, Hong Kong, Peoples R China

[4] Changzhou Univ, Key Lab Fine Petrochem Technol, Changzhou 213164, Peoples R China

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 37期

基金：

美国国家科学基金会;

关键词：

LANTHANIDE ION COMPLEXES; SOLID-STATE CLASS; CRYSTAL-STRUCTURES; SILVER DICYANIDES; TETRA-DECKER; PHOTOLUMINESCENCE; COORDINATION; GOLD;

D O I：

10.1039/c2dt31268a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two hexanuclear 3d-4f Ni-Eu and Cu-Eu complexes [Eu4Ni2L2(OAc)(12)(EtOH)(2)] (1) and [Eu4Cu2L2(OAc)(12)]center dot 2H(2)O (2) are reported which are formed from the salen type Schiff-base ligand H2L (H2L = N,N'-bis(3-methoxysalicylidene)butane-1,4-diamine). In both complexes, four Eu3+ cations are bridged by eight OAc- groups and the chain is terminated at each end by two ML (M = Ni and Cu) units. The structures of 1 and 2 were determined by single crystal X-ray crystallographic studies and the luminescence properties of the free ligand and metal complexes in solution were measured.

引用

页码：11449 / 11453

页数：5

共 50 条

[1] Synthesis and structural characterization of dinuclear 3d-4f complexes, dinuclear (Eu), tetranuclear (Ni), and hexanuclear (Dy) complexes of a Schiff base ligand
Bunge, Scott
Tandon, Santokh
Hogan, Vivian
Boyle, Rebecca
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[2] Heterobimetallic 3d-4f complexes supported by a Schiff-base tripodal ligand
Neumann, Till
Thompson, Benedict C.
Hebron, Denny
Graycon, Daniel M.
Collauto, Alberto
Roessler, Maxie M.
Wilson, Daniel W. N.
Musgrave, Rebecca A.
DALTON TRANSACTIONS, 2024, 53 (23) : 9921 - 9932
[3] Construction of 1-D 4f and 3d-4f coordination polymers with flexible Schiff base ligands
Yang, Xiaoping
Lam, Daniel
Chan, Christopher
Stanley, Julie M.
Jones, Richard A.
Holliday, Bradley J.
Wong, Wai-Kwok
DALTON TRANSACTIONS, 2011, 40 (38) : 9795 - 9801
[4] Anion-Dependent Assembly of Heterometallic 3d-4f Clusters Based on a Lacunary Polyoxometalate
Cai, Jing
Zheng, Xiu-Ying
Xie, Jing
Yan, Zhi-Hao
Kong, Xiang-Jian
Ren, Yan-Ping
Long, La-Sheng
Zheng, Lan-Sun
INORGANIC CHEMISTRY, 2017, 56 (14) : 8439 - 8445
[5] Anion-dependent substitution of zinc by magnesium in mononuclear Schiff base complexes
Hermann, J
Schumacher, D
Erxleben, A
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2002, (09) : 2276 - 2280
[6] Unexplored analytics of some novel 3d-4f heterometallic Schiff base complexes
Chakrabarty, Partha Pratim
Saha, Sandip
Sen, Kamalika
Jana, Atish Dipankar
Dey, Debarati
Schollmeyer, Dieter
Garcia-Granda, Santiago
RSC ADVANCES, 2014, 4 (77) : 40794 - 40802
[7] Di- or Trinuclear 3d-4f Schiff Base Complexes: The Role of Anions
Costes, Jean-Pierre
Donnadieu, Bruno
Gheorghe, Ruxandra
Novitchi, Ghenadie
Tuchagues, Jean-Pierre
Vendier, Laure
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (33) : 5235 - 5244
[8] Structures and Magnetic Properties of Three Heterobimetallic 3d-4f Hexanuclear Complexes
Fu, Xiao-Xiao
Wang, Hai-Ling
Zou, Hua-Hong
Quan, Han-Bai
Li, Bo
Liang, Fu-Pei
JOURNAL OF CLUSTER SCIENCE, 2017, 28 (06) : 3229 - 3239
[9] Chiral 4f and 3d-4f Complexes from Enantiopure Salen-Type Schiff Base Ligands
Raptopoulou, Catherine P.
CRYSTALS, 2024, 14 (05)
[10] Synthesis and near-infrared luminescence of 3d-4f bi-metallic Schiff base complexes
Wong, WK
Liang, HZ
Wong, WY
Cai, ZW
Li, KF
Cheah, KW
NEW JOURNAL OF CHEMISTRY, 2002, 26 (03) : 275 - 278

← 1 2 3 4 5 →