Dibenzoarsacrowns: an experimental and computational study on the coordination behaviors

被引:6
|
作者
Sumida, Akifumi [1 ]
Kobayashi, Ryosuke [1 ]
Yumura, Takashi [2 ]
Imoto, Hiroaki [1 ,3 ]
Naka, Kensuke [1 ,3 ]
机构
[1] Kyoto Inst Technol, Fac Mol Chem & Engn, Sakyo Ku, Goshokaido Cho, Kyoto 6068585, Japan
[2] Kyoto Inst Technol, Fac Mat Sci & Technol, Sakyo Ku, Goshokaido Cho, Kyoto 6068585, Japan
[3] Kyoto Inst Technol, Mat Innovat Lab, Sakyo Ku, Goshokaido Cho, Kyoto 6068585, Japan
关键词
D O I
10.1039/d0cc07191a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dibenzoarsacrowns have been synthesized as a novel class of heteroatom-fused crown ethers. The dibenzoarsacrowns can size-selectively capture alkali metal cations, and the arsenic atoms chemoselectively coordinated to gold(I) chloride (AuCl) due to the soft Lewis acid-base interaction. It is notable that the AuCl complex of 21-dibenzoarsacrown-7 further encapsulated Na+ with the enhanced association constant from bare 21-dibenzoarsacrown-7. The positive allosteric effect was studied computationally.
引用
收藏
页码:2013 / 2016
页数:4
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