Crystal structures of (Et4N)2C2S6, (Et4N)2C2S5, (Et4N)2CS4, (Et4N)HCS3, (Et4N)2CS3•2H2O and (Et4N)2CS4-y•yH2O (y=0.69).

被引:1
|
作者
Bernhardt, Eduard [1 ]
机构
[1] Berg Univ Wuppertal, Anorgan Chem, Fak Math & Nat Wissensch, Gaussstr 20, D-42119 Wuppertal, Germany
来源
关键词
Thiocarbonate; Perthiocarbonate; Tetraethylammonium; ELECTROCHEMICAL PREPARATION; TRITHIOCARBONATE; PERTHIOCARBONATE; MONOHYDRATE; COMPLEXES; ADDUCT; ANION;
D O I
10.1002/zaac.202100001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structures of (Et4N)(2)C2S6, (Et4N)(2)C2S5, (Et4N)(2)CS4, (Et4N)HCS3, (Et4N)(2)CS3 center dot 2H(2)O and (Et4N)(2)CS4-y center dot yH(2)O (y=0.69) were determined by single-crystal X-ray diffraction analysis at 150 K. For the first time, salts with the C2S52- and HCS3- anions could be synthesized.
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页码:777 / 782
页数:6
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