Compositions, Densities, and Refractive Indices for the Ternary Systems Ethylene Glycol + NaCl + H2O, Ethylene Glycol + KCl + H2O, Ethylene Glycol + RbCl + H2O, and Ethylene Glycol + CsCl + H2O at 298.15 K

被引：22

作者：

Zhou, Yanhong ^{[1
]}

Li, Shu'ni ^{[1
]}

Zhai, Quanguo ^{[1
]}

Jiang, Yucheng ^{[1
]}

Hu, Mancheng ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 03期

基金：

中国国家自然科学基金;

关键词：

LIQUID-SOLID EQUILIBRIA; PLUS SODIUM-CHLORIDE; SATURATED SOLUTIONS; POTASSIUM-CHLORIDE; RUBIDIUM-CHLORIDE; WATER; ETHANOL; SOLUBILITY; ISOTHERMS; VISCOSITY;

D O I：

10.1021/je900630n

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Solubilities, densities, and refractive indices have been measured for the four ternary systems, ethylene glycol + NaCl + H2O, ethylene glycol + KCl + H2O, ethylene glycol + RbCl + H2O, and ethylene glycol + CsCl + H2O, at T = 298.15 K, with mass fractions of ethylene glycol ranging from 0 to 1.0. Polynomial equations of fit are proposed for the solubility of the saturated solutions IS a function of the mass fraction of ethylene glycol. The equations proposed also account for the density and refractive index for the saturated Solutions. Oil the other hand, the density and refractive index of unsaturated Solutions Were also determined for the same ternary systems with varied undersaturated salt concentrations. Values for both the properties were also correlated with the salt concentrations and proportions of ethylene glycol in the undersaturated Solutions. In all the cases, the presence of ethylene glycol significantly reduces the solubility Of the Salts in the aqueous solution.

引用

页码：1289 / 1294

页数：6

共 50 条

[1] The influence of ethylene glycol on the preparation of K2SnSi3O9•H2O
Lin, Zhi
ZEOLITES AND RELATED MATERIALS: TRENDS, TARGETS AND CHALLENGES, PROCEEDINGS OF THE 4TH INTERNATIONAL FEZA CONFERENCE, 2008, 174 : 301 - 304
[2] The influence of ethylene glycol on the preparation of K2SnSi3O9·H2O
Lin, Zhi
Studies in Surface Science and Catalysis, 2008, 174 (0A) : 301 - 304
[3] Base fluid and temperature effects on the heat transfer characteristics of SiC in ethylene glycol/H2O and H2O nanofluids
Timofeeva, Elena V.
Yu, Wenhua
France, David M.
Singh, Dileep
Routbort, Jules L.
JOURNAL OF APPLIED PHYSICS, 2011, 109 (01)
[4] Solubilities, Densities, and Refractive Indices of the Ternary Systems KCl + RbCl + H2O and KCl + MgCl2 + H2O at 348.15 K
Yu, Xudong
Zeng, Ying
Yin, Qinghong
Mu, Pengtao
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2012, 57 (12): : 3658 - 3663
[5] Solubilities, densities and refractive indices for the ternary systems ethylene glycol + MCl + H2O (M = Na, K, Rb, Cs) at (15 and 35)°C
Zhou, Yan-Hong
Li, Shu-Ni
Zhai, Quan-Guo
Jiang, Yu-Cheng
Hu, Man-Cheng
JOURNAL OF CHEMICAL THERMODYNAMICS, 2010, 42 (06): : 764 - 772
[6] Metastable Phase Equilibria in the Aqueous Ternary Systems KCl + MgCl2 + H2O and KCl + RbCl + H2O at 298.15 K
Yu, Xudong
Zeng, Ying
Yao, Huixin
Yang, Jianyuan
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (08): : 3384 - 3391
[7] Effect of Ethylene Glycol on the Molecular Organization of H2O in Comparison with Methanol and Glycerol: A Calorimetric Study
Yoshikata Koga
Journal of Solution Chemistry, 2003, 32 : 803 - 818
[8] Effect of ethylene glycol on the molecular organization of H2O in comparison with methanol and glycerol:: A calorimetric study
Koga, Y
JOURNAL OF SOLUTION CHEMISTRY, 2003, 32 (09) : 803 - 818
[9] Corrosion behavior of iron-based alloys in the LiBr plus ethylene glycol + H2O mixture
Samiento-Bustos, E.
Gonzalez-Rodriguez, J. G.
Uruchurtu, J.
Salinas-Bravo, V. M.
CORROSION SCIENCE, 2009, 51 (05) : 1107 - 1114
[10] High-frequency dynamical behavior of poly(ethylene glycol)+H2O mixtures by Brillouin spectroscopy
Pochylski, M.
Aliotta, F.
Blaszczak, Z.
Gapinski, J.
MACROMOLECULAR SYMPOSIA, 2007, 251 : 47 - 53

← 1 2 3 4 5 →