Molecular properties of comb-shaped polymers with cyanobiphenyl mesogenic side groups

被引：0

作者：

Lavrenko, PN

Evlampieva, NP

Polushin, SG

Okatova, OV

Knochenhauer, G

Kalnin'sh, KK

Lacey, D

Hall, AW

机构：

[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia

[2] St Petersburg State Univ, Inst Phys, Petrodvorets Branch, Petrodvorets 198904, Russia

[3] Univ Potsdam, Res Ctr Thin Organ & Biochem Films, D-14513 Teltow, Germany

[4] Univ Hull, Sch Chem, Fac Sci & Environm, Hull HU6 7RX, N Humberside, England

来源：

VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 2000年 / 42卷 / 03期

关键词：

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The electrooptical, dielectric, and hydrodynamic properties of two new comb-shaped LC polymers in benzene and chloroform solutions were studied. The monomer group of a polymer contains a polar group (-CN- or -COCH3-) in the backbone and a hydroxyl group in a spacer linking a cyanobiphenyl side mesogenic group to the backbone. The electrooptical and dielectric properties of the synthesized polymers are compared with the properties of the homologous series of alkoxycyanobiphenyls, which model the side chains of the polymers under study. The observed difference in the values of the Kerr constant is explained by a different mobility of the side mesogenic groups in the studied polymers, which is related to the specific features of the chemical and dipole structures of macromolecules.

引用

页码：497 / 504

页数：8

共 50 条

[1] Photoregulation of the optical properties of comb-shaped polymers with mesogenic side groups
Shibaev, V
Kostromin, S
Ivanov, S
MACROMOLECULAR SYMPOSIA, 1997, 118 : 493 - 496
[2] Photoregulation of the optical properties of comb-shaped polymers with mesogenic side groups and the problems of data recording
Shibaev, VP
Kostromin, SG
Ivanov, SA
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1997, 39 (01): : 43 - 62
[3] The effect of silver nanoparticles on the phase state of comb-shaped liquid crystalline polymers with cyanobiphenyl mesogenic groups
Barmatov, E. B.
Medvedev, A. S.
Pebalk, D. A.
Barmatova, M. B.
Nikonorova, N. A.
Zezin, S. B.
Shibaev, V. P.
POLYMER SCIENCE SERIES A, 2006, 48 (07) : 665 - 675
[4] The effect of silver nanoparticles on the phase state of comb-shaped liquid crystalline polymers with cyanobiphenyl mesogenic groups
E. B. Barmatov
A. S. Medvedev
D. A. Pebalk
M. B. Barmatova
N. A. Nikonorova
S. B. Zezin
V. P. Shibaev
Polymer Science Series A, 2006, 48 : 665 - 675
[5] Hydrodynamic, optical, and conformational properties of a comb-shaped polymer with cyanobiphenyl groups in the side chains
Tsvetkov, VN
Bushin, SV
Andreeva, LN
Belyaeva, EV
Bezrukova, MA
Astapenko, EP
Barmatov, EB
Shibaev, VP
POLYMER SCIENCE SERIES A, 2000, 42 (07) : 706 - 713
[6] Optically isotropic mesophase in comb-shaped copolymers with side mesogenic groups
Barmatov, E. B.
Pebalk, D. A.
Barmatova, M. V.
POLYMER SCIENCE SERIES A, 2007, 49 (02) : 148 - 157
[7] Optically isotropic mesophase in comb-shaped copolymers with side mesogenic groups
E. B. Barmatov
D. A. Pebalk
M. V. Barmatova
Polymer Science Series A, 2007, 49 : 148 - 157
[8] DIELECTRIC-RELAXATION IN LIQUID-CRYSTALLINE COMB-SHAPED POLYMERS WITH CYANOBIPHENYL GROUPS IN THE SIDE-CHAINS
NIKONOROVA, NA
BORISOVA, TI
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1993, 35 (01): : B39 - B43
[9] Dynamic and electric birefringence in solutions of a comb-shaped polymer with mesogenic side groups
Kolomiets, I.P.
Lavrenko, P.N.
Lezov, A.V.
Ovsipyan, A.M.
Finkel'mann, Kh.
Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 1993, 35 (10): : 1620 - 1624
[10] The nature of electrooptical effect in solutions of a comb-shaped polymer with mesogenic side groups
Lezov, A.V.
Mikhajlova, M.E.
Kovshik, S.A.
Polushina, G.E.
Ryumtsev, E.I.
Vysokomolekularnye Soedineniya. Ser.A Ser.B Ser.C - Kratkie Soobshcheniya, 2003, 45 (07): : 1123 - 1129

← 1 2 3 4 5 →