Naphtho[1,8-b,c]phosphete and 1,2-diphosphaacenaphthene from the reaction of 1,8-dilithionaphthalene with RPCl2

被引：0
|
作者：
Mizuta, T [1 ]
Nakazono, T [1 ]
Miyoshi, K [1 ]
机构：
[1] Hiroshima Univ, Dept Chem, Grad Sch Sci, Higashihiroshima 7398526, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 20期
关键词：
heterocycles; metallacycles; P ligands; small ring systems; tungsten;
D O I：
10.1002/1521-3773(20021018)41:20<3897::AID-ANIE3897>3.0.CO;2-H
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Strained rings and metal insertions: The product ot the reaction between 1,8-dilithionaphthalene and RPCl2 differs depending on the R group on the phosphorus atom. PhPCl2 gave (PhP)2-peri-bridged naphthalene, while iPr2NPCl2 gave the iPr2-bridged compound (see scheme). The reactivity of the new compounds with transition-metal complexes is also discussed.
引用
收藏
页码：3897 / 3898
页数：2
相关论文
共 50 条
  • [1] PERI-BRIDGED NAPHTHALENES FROM 1,8-DILITHIONAPHTHALENE
    MEINWALD, J
    DAUPLAISE, D
    WUDL, F
    HAUSER, JJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (01) : 255 - 257
  • [2] SYNTHESIS, CRYSTAL, AND MOLECULAR-STRUCTURES AND CONFORMATIONS OF NAPHTHO[1,8-B,C]-1,5-DITHIOCIN-1,1-DIOXIDE, NAPHTHO[1,8-B,C]-1,5-DITHIOCIN-1,5-DIOXIDE, NAPHTHO[1,8-B,C]-1,5-DITHIOCIN-1,1,5-TRIOXIDE AND NAPHTHO[1,8-B,C]-1,5-DITHIOCIN-1,1,5,5-TETRAOXIDE
    GLASS, RS
    BROEKER, JL
    TETRAHEDRON, 1991, 47 (28) : 5077 - 5086
  • [3] Napatho(LSQB)1-8-bc(RSQB) phosphete and 1,2-diphosphaacenaphthene from the reaction of 1-8-dilithionaphthalene with RPC12 (vol 41, pg 3897, 2002)
    Mizuta, T
    Nakazono, T
    Miyoshi, K
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (07) : 712 - 712
  • [4] SULFONATION OF NAPHTHO[1,8-B,C]THIOPHEN-2-ONE BY DIMETHYL SULFATE
    ROZHINSKII, YI
    PLAKIDIN, VL
    ZHURNAL ORGANICHESKOI KHIMII, 1981, 17 (08): : 1783 - 1784
  • [5] 1,2-Diphosphaacenaphthene 1,2-Dications: Synthetic, Stereochemical and Computational Study of the Stabilising Role of Naphthalene-1,8-diyl Backbone
    Somisara, D. M. Upulani K.
    Buehl, Michael
    Lebl, Tomas
    Richardson, Neville V.
    Slawin, Alexandra M. Z.
    Woollins, J. Derek
    Kilian, Petr
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (09) : 2666 - 2677
  • [6] FLASH-PHOTOLYSIS STUDY OF THE MECHANISM OF PHOTOCHROMISM OF NAPHTHO[1,8-B,C]FURAN SPIROPYRANS
    DVORNIKOV, AS
    MALKIN, YN
    MEZHERITSKII, VV
    ZHUKOVSKAYA, ON
    REVINSKII, YV
    KUZMIN, VA
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1982, 31 (09): : 1778 - 1782
  • [7] SULFUR SULFUR LONE PAIR AND SULFUR NAPHTHALENE INTERACTIONS IN NAPHTHO[1,8-B,C]-1,5-DITHIOCIN
    GLASS, RS
    ANDRUSKI, SW
    BROEKER, JL
    FIROUZABADI, H
    STEFFEN, LK
    WILSON, GS
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (11) : 4036 - 4045
  • [8] SYMMETRICAL DYES - DERIVATIVES OF NAPHTO[1,8-B,C]THIOPHENE
    VASILENKO, NP
    MIKHAILENKO, FA
    MAIDANNIK, AG
    KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1987, (03): : 418 - 419
  • [9] CONFORMATIONAL-ANALYSIS OF NAPHTHO[1,8-B,C]-1,5-DITHIOCIN AND ITS S-OXIDES IN SOLUTION
    GLASS, RS
    BROEKER, JL
    TETRAHEDRON, 1991, 47 (28) : 5087 - 5098
  • [10] NAPHTHO[1,8-CD-4,5-C'D']BIS[1,2]DISELENOLE
    YAMAHIRA, A
    NOGAMI, T
    MIKAWA, H
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (16) : 904 - 905
12345