Characterization of synthetic carbons activated with phosphoric acid

被引：40
|
作者：
Puziy, AM
Poddubnaya, OI
Martínez-Alonso, A
Suárez-García, F
Tascón, JMD
机构：
[1] Inst Sorpt & Problems Endoecol, UA-03164 Kiev, Ukraine
[2] CSIC, Inst Nacl Carbon, E-33080 Oviedo, Spain
来源：
APPLIED SURFACE SCIENCE | 2002年 / 200卷 / 1-4期
关键词：
synthetic carbons; chemical activation; adsorption modeling; pore-size distribution;
D O I：
10.1016/S0169-4332(02)00883-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The structural heterogeneity of synthetic phosphoric acid activated carbons has been analyzed using pore-size distributions (PSDs) obtained from nitrogen at - 196 degreesC and carbon dioxide at 0 degreesC isotherms. PSDs where obtained by the BET-Kelvin method. It is shown that the BET-Kelvin method is in good agreement with DFT and provides a fast means for assessment of the porous structure of adsorbents. PSDs obtained by the BET-Kelvin method using different adsorbates give results consistent with each other. Due to the restricted pressure range for carbon dioxide adsorption isotherm the PSD gives information only about pores in the micropore range. The agreement between different methods is better for small micropores. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：196 / 202
页数：7
相关论文
共 50 条
  • [1] Synthetic carbons activated with phosphoric acid III.: Carbons prepared in air
    Puziy, AM
    Poddubnaya, OI
    Martínez-Alonso, A
    Suárez-García, F
    Tascón, JMD
    [J]. CARBON, 2003, 41 (06) : 1181 - 1191
  • [2] Synthetic carbons activated with phosphoric acid -: II.: Porous structure
    Puziy, AM
    Poddubnaya, OI
    Martínez-Alonso, A
    Suárez-García, F
    Tascón, JMD
    [J]. CARBON, 2002, 40 (09) : 1507 - 1519
  • [3] Synthetic carbons activated with phosphoric acid -: I.: Surface chemistry and ion binding properties
    Puziy, AM
    Poddubnaya, OI
    Martínez-Alonso, A
    Suárez-García, F
    Tascón, JMD
    [J]. CARBON, 2002, 40 (09) : 1493 - 1505
  • [4] POROSITY IN GRANULAR CARBONS ACTIVATED WITH PHOSPHORIC-ACID
    MOLINASABIO, M
    RODRIGUEZREINOSO, F
    CATURLA, F
    SELLES, MJ
    [J]. CARBON, 1995, 33 (08) : 1105 - 1113
  • [5] XPS and NMR studies of phosphoric acid activated carbons
    Puziy, A. M.
    Poddubnaya, O. I.
    Socha, R. P.
    Gurgul, J.
    Wisniewski, M.
    [J]. CARBON, 2008, 46 (15) : 2113 - 2123
  • [6] PREPARATION AND CHARACTERIZATION OF ACTIVATED CARBONS FROM COCONUT SHELL IMPREGNATED WITH PHOSPHORIC-ACID
    LAINE, J
    CALAFAT, A
    LABADY, M
    [J]. CARBON, 1989, 27 (02) : 191 - 195
  • [7] STUDY OF SORPTION PROPERTIES OF CARBONS ACTIVATED BY PHOSPHORIC-ACID
    AMELIN, AN
    KARYAKIN, YV
    [J]. ZHURNAL PRIKLADNOI KHIMII, 1973, 46 (08) : 1851 - 1852
  • [8] Preparation and characterization of activated carbons obtained from the waste materials impregnated with phosphoric acid(V)
    Magdalena Zięzio
    Barbara Charmas
    Katarzyna Jedynak
    Monika Hawryluk
    Karolina Kucio
    [J]. Applied Nanoscience, 2020, 10 : 4703 - 4716
  • [9] Preparation and characterization of activated carbons obtained from the waste materials impregnated with phosphoric acid(V)
    Ziezio, Magdalena
    Charmas, Barbara
    Jedynak, Katarzyna
    Hawryluk, Monika
    Kucio, Karolina
    [J]. APPLIED NANOSCIENCE, 2020, 10 (12) : 4703 - 4716
  • [10] Preparation and Characterization of Activated Carbons from Biomass-based Carbon through Phosphoric Acid Activation
    Zhang Zhi
    Yu Zhimin
    Wu Ke
    Chen Peirong
    [J]. PROCEEDINGS OF THE 4TH INTERNATIONAL CONFERENCE ON ENVIRONMENTAL TECHNOLOGY AND KNOWLEDGE TRANSFER, 2012, : 661 - 666
12345