Spectral absorptions on Phobos and Deimos in the visible/near infrared wavelengths and their compositional constraints

Absorption features on Phobos and Deimos in the visible/near infrared wavelength region (0.4-3.9 mu m) are mapped using observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Fe2+ electronic absorptions diagnostic of olivine and pyroxene are not detected. A broad absorption centered around 0.65 mu m within the red spectral units of both moons is detected, and this feature is also evident in telescopic, Pathfinder, and Phobos-2 observations of Phobos. A 2.8 mu m metal-OH combination absorption on both moons is also detected in the CRISM data, and this absorption is shallower in the Phobos blue unit than in the Phobos red unit and Deimos. The strength, position, and shape of both of the 0.65 mu m and 2.8 mu m absorptions are similar to features seen on red-sloped, low-albedo primitive asteroids. Two end-member hypotheses are presented to explain the spectral features on Phobos and Deimos. The first invokes the presence of highly desiccated Fe-phyllosilicate minerals indigenous to the bodies, and the second invokes Rayleigh scattering and absorption of small iron particles formed by exogenic space weathering processing, coupled with implantation of H from solar wind. Both endmember hypotheses may play a role, and in situ exploration will be needed to ultimately determine the underlying causes for the pair of spectral features observed on Phobos and Deimos. (C) 2013 Elsevier Inc. All rights reserved.