lithium air battery;
saturation;
X-ray micro-computed tomography;
digital twin;
NICKEL IONS;
DIFFUSION;
MIGRATION;
D O I:
10.3390/en15196986
中图分类号:
TE [石油、天然气工业];
TK [能源与动力工程];
学科分类号:
0807 ;
0820 ;
摘要:
In this paper, the saturation of electrolytes on the mass transfer property of porous electrodes in non-aqueous lithium air batteries has been studied based on digital twin. Herein, we reconstruct the porous cathode based on X-ray micro-computed tomography (mu ct) and quantitatively analyze the pore size distribution, specific surface area, triple-phase interface area, conductivity and diffusion coefficient of reactants at varying filling degrees of the electrolyte. The results derived from digital twin provide insight into the gas-liquid two-phase mass transfer performance in the porous cathode with various degrees of electrolyte saturation and demonstrate that the optimum electrolyte saturation is 60%.
机构:
Dongguk Univ Seoul, Dept Energy & Mat Engn, Seoul 100715, South KoreaUniv Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
机构:
Dongguk Univ Seoul, Dept Energy & Mat Engn, Seoul 100715, South KoreaUniv Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
机构:
Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, JapanNatl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
Wang, Yonggang
He, Ping
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机构:
Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, JapanNatl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
He, Ping
Zhou, Haoshen
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机构:
Natl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, JapanNatl Inst Adv Ind Sci & Technol, Energy Technol Res Inst, Tsukuba, Ibaraki 3058568, Japan
机构:
Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R ChinaSichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R China
Zhang, Kaifang
Mu, Shijia
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机构:
Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R ChinaSichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R China
Mu, Shijia
Liu, Wei
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机构:
Sichuan Univ, Inst New Energy & Low Carbon Technol, Chengdu 610207, Sichuan, Peoples R ChinaSichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R China
Liu, Wei
Zhu, Ding
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机构:
Sichuan Univ, Inst New Energy & Low Carbon Technol, Chengdu 610207, Sichuan, Peoples R ChinaSichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R China
Zhu, Ding
Ding, Zhendong
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机构:
Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R ChinaSichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R China
Ding, Zhendong
Chen, Yungui
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机构:
Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R China
Sichuan Univ, Inst New Energy & Low Carbon Technol, Chengdu 610207, Sichuan, Peoples R ChinaSichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Sichuan, Peoples R China