New Photochromic Salt Spiropyrans of Indoline Series

被引:2
|
作者
Pugachev, A. D. [1 ]
Lukyanova, M. B. [1 ]
Tkachev, V. V. [2 ]
Lukyanov, B. S. [1 ,3 ]
Makarova, N., I [1 ]
Shilov, G., V [2 ]
Rostovtseva, I. A. [1 ]
Lapshina, L. S. [3 ]
Minkin, V., I [1 ]
Aldoshin, S. M. [2 ]
机构
[1] Southern Fed Univ, Res Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
[3] Don State Tech Univ, Rostov Na Donu 344000, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/S0012500819020113
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis, structure study, and photochromic properties of new salt spiropyrans of indoline series containing chlorine and bromine atoms in the 6'-position of the 2H-chromene moiety have been reported. The structure of the obtained compounds has been confirmed by H-1 NMR spectroscopy and X-ray diffraction analysis. The compounds are photochromic; the long-wavelength absorption maximum for photoinduced isomer shows a considerable hypsochromic shift, while the lifetime increases considerably as compared with the fluorine-containing analog.
引用
收藏
页码:58 / 63
页数:6
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