Influential factors on assembly of first-row transition metal coordination polymers

被引：27
|
作者：
Yang, Shi-Yao [1 ]
Yuan, Hong-Bo [1 ,2 ]
Xu, Xiao-Bin [1 ,3 ]
Huang, Rong-Bin [1 ]
机构：
[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China
[2] Shandong Career Dev Coll, Jining 272021, Shandong, Peoples R China
[3] North Fujian Vocat & Tech Coll, Fuzhou, Fujian, Peoples R China
来源：
INORGANICA CHIMICA ACTA | 2013年 / 403卷
关键词：
Metal centre; Ion radius; Benzene dicarboxylic acid; Metal-organic framework; Crystal engineering; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; BUILDING UNITS; DESIGN; TEMPERATURE; TOPOLOGIES; HYDROGEN; METHANE; STORAGE; MOFS;
D O I：
10.1016/j.ica.2013.03.042
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Herein, twenty-seven coordination polymers were synthesised using Mn2+, Co2+, Ni2+, Cu2+ and Zn2+ in organic solvents. Structural analyses show that metal ions are the most important factor that influences coordination polymer assembly. Metal ions determine the type of metal centre and structural topology. The organic ligand benzene dicarboxylic acid is the second most influential factor. Synthetic conditions are not key factors in this research system. (C) 2013 Elsevier B. V. All rights reserved.
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收藏
页码：53 / 62
页数：10
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