Synthesis and Characterization of Polyesters from Glycerol by-Product of Biodiesel Production

被引：10

作者：

Rodarte de Moura, Carla V. ^{[1
]}

Nunes, Antonia S. L. ^{[1
]}

Moita Neto, Jose M. ^{[1
]}

Neres, Haroldo L. S. ^{[1
]}

de Carvalho, Lee M. G. ^{[1
]}

de Moura, Edmilson M. ^{[1
]}

机构：

[1] Univ Fed Piaui, Dept Quim, BR-64049550 Teresina, PI, Brazil

来源：

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY | 2012年 / 23卷 / 07期

关键词：

glycerol; resins; biodiesel; HYDROGEN-PRODUCTION; DENSITY; ACID;

D O I：

10.1590/S0103-50532012000700005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Glycerol, a by-product from biodiesel production can react with di-carboxylic organic acids, resulting in polyesters, and can be used in the composition of urea/formaldehyde or phenol/formaldehyde resins to improve the qualities of adhesion and moisture resistance of them. In this work, six kinds of resins derived from glycerol, named as GAA (glycerol/adipic acid), GAAU (glycerol/adipic acid/urea), GAF (glycerol/phtalic acid), GU (glycerol/urea), GUF (glycerol/urea/formaldehyde) and GF (glycerol/formaldehyde), were synthesized. The resins derived from carboxylic acids had better thermal stability (up to 350 degrees C) than those derived from formaldehyde (up to 200 degrees C). The average molecular weights of the resins were determined by matrix assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF MS) and gel-permeation chromatography (GPC), and are in the range of 1800-2800 Da, being oligomers, and the polydispersity indexes are in the range of 1.3 to 1.8. The H-1 and C-13 nuclear magnetic resonance (NMR) techniques were used to identify the structure of the resins.

引用

页码：1226 / 1231

页数：6

共 50 条

[1] Synthesis of Glycerol Carbonate from Glycerol, a By-Product of Biodiesel Production
Herseczki, Zsanett
Varga, Tamas
Marton, Gyula
[J]. INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2009, 7
[2] Synthesis of glycerol carbonate from glycerol, a by-product of biodiesel production
Herseczki, Zsanett
Varga, Tamás
Marton, Gyula
[J]. International Journal of Chemical Reactor Engineering, 2009, 7
[3] SYNTHESIS OF TRIPROPIONIN FROM CRUDE GLYCEROL THE BY-PRODUCT OF BIODIESEL PRODUCTION
Herseczki, Zsanett
Marton, Gyula
Dallos, Andras
[J]. STUDIA UNIVERSITATIS BABES-BOLYAI CHEMIA, 2013, 58 (02): : 7 - 22
[4] Sustainable Production of Glycerol Carbonate from By-product in Biodiesel Plant
Galadima, Ahmad
Muraza, Oki
[J]. WASTE AND BIOMASS VALORIZATION, 2017, 8 (01) : 141 - 152
[5] Sustainable Production of Glycerol Carbonate from By-product in Biodiesel Plant
Ahmad Galadima
Oki Muraza
[J]. Waste and Biomass Valorization, 2017, 8 : 141 - 152
[6] Synthesis of glycerol carbonate from biodiesel by-product glycerol over calcined dolomite
Algoufi, Y. T.
Kabir, G.
Hameed, B. H.
[J]. JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2017, 70 : 179 - 187
[7] Synthesis of racemic lactide using glycerol by-product from biodiesel fuel production process as feedstock
Hasegawa, Takashi
Nomura, Nobuyoshi
Moriya, Takehiko
Nishikawa, Hitoshi
Yamaguchi, Syuhei
Kishida, Hisanori
[J]. 11TH ECO-ENERGY AND MATERIALS SCIENCE AND ENGINEERING (11TH EMSES), 2014, 56 : 195 - 200
[8] Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol
Leoneti, Alexandre Bevilacqua
Aragao-Leoneti, Valquiria
Walter Borges de Oliveira, Sonia Valle
[J]. RENEWABLE ENERGY, 2012, 45 : 138 - 145
[9] Enzymatic production of glycerol carbonate from by-product after biodiesel manufacturing process
Jung, Hongsub
Lee, Youngrak
Kim, Daeheum
Han, Sung Ok
Kim, Seung Wook
Lee, Jinwon
Kim, Yong Hwan
Park, Chulhwan
[J]. ENZYME AND MICROBIAL TECHNOLOGY, 2012, 51 (03) : 143 - 147
[10] Optimization of compost fermentation of glycerol by-product discharged from biodiesel fuel production process
Sadano, Yuta
Toshimitsu, Ryota
Kohda, Jiro
Nakano, Yasuhisa
Yano, Takuo
[J]. JOURNAL OF MATERIAL CYCLES AND WASTE MANAGEMENT, 2010, 12 (04) : 308 - 313

← 1 2 3 4 5 →