Chiral synthons from carvone .24. Photochemical rearrangements of chiral bicyclo[2.2.2]oct-5-en-2-ones

被引：3
|
作者：
Srikrishna, A
Danieldoss, S
机构：
[1] Department of Organic Chemistry, Indian Institute of Science
来源：
SYNTHETIC COMMUNICATIONS | 1997年 / 27卷 / 04期
关键词：
D O I：
10.1080/00397919708003339
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Photochemical oxadi-pi-methane rearrangement (1,2-acyl shift) of the chiral bicyclo[2.2.2]oct-5-en-2-ones 2 and 3 furnishes the tricyclic ketones 5 and 6, whereas the 1,3-acyl shift generates the cyclobutanones 7 and 8 respectively.
引用
收藏
页码：655 / 661
页数：7
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