Analytical procedures for short chain chlorinated paraffins determination - How to make them greener?

被引:11
|
作者
Kalinowska, Kaja [1 ]
Lenartowicz, Pawel [2 ]
Namiesnik, Jacek [1 ]
Marc, Mariusz [1 ,3 ]
机构
[1] Gdansk Univ Technol, Dept Analyt Chem, Fac Chem, Ul G Narutowicza 11-12, PL-80233 Gdansk, Poland
[2] Wroclaw Univ Sci & Technol, Dept Bioorgan Chem, Fac Chem, Wroclaw, Poland
[3] Opole Univ, Fac Chem, Dept Analyt & Ecol Chem, Opole, Poland
关键词
Short-chain chlorinated paraffins; Green analytical chemistry; Sample preparation techniques; Environmental samples; Gas chromatography; Results quality; RESOLUTION MASS-SPECTROMETRY; WASTE DISMANTLING AREA; PEARL RIVER DELTA; OF-THE-ART; SEDIMENT SAMPLES; N-ALKANES; POLYCHLORINATED-BIPHENYLS; ENVIRONMENTAL-SAMPLES; SPATIAL-DISTRIBUTION; GAS-CHROMATOGRAPHY;
D O I
10.1016/j.scitotenv.2019.03.312
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The aim of the following paper was to gather current scientific information about the analytical protocols dedicated tomeasuring the content level of short-chain chlorinated paraffins (SCCPs) in various types of environmental samples. Moreover, the data about the basic validation parameters of applied procedures for SCCPs determination are listed. The main issue which is highlighted in the paper is the possibility of the application of green analytical chemistry (GAC) principals in the SCCPs measuring process to reduce the environmental impact of the applied methodology. Analytical methods dedicated to SCCPs determination contain a significant number of steps and require advanced analytical equipment during the quantitative and qualitative analysis. In addition, there is a substantial issue associated with the reliability of the obtained results, especially in the case of the quantification of individual SCCPs in the studied samples. Due to this fact, the paper attempts to discuss the various stages of the analytical procedure, in which appropriate changes in the formula or equipment solutions might be introduced to ensure a better quality of the analytical results, as well as to meet the requirements of the philosophy of green analytical chemistry. The most important case which concerns this subject is finding an optimal consensus between the economic and logistic aspects and the quality and "greenness" of the analytical procedure employed in SCCPs determination process. (C) 2019 Elsevier B.V. All rights reserved.
引用
收藏
页码:309 / 323
页数:15
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