Advances and prospects of rare earth metal-organic frameworks in catalytic applications

被引:72
|
作者
Sun, Xiaochen [1 ]
Yuan, Kun [1 ]
Zhang, Yawen [1 ]
机构
[1] Peking Univ, PKU HKU Joint Lab Rare Earth Mat & Bioinorgan Che, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci,Coll Chem & Mol Engn, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
Rare earth metal-organic frameworks; Synthesis methodology; Heterogeneous catalysis; Photocatalysis; LEWIS-ACID CATALYSIS; C-C; PHOTOCATALYTIC DEGRADATION; PALLADIUM NANOPARTICLES; SUPPORT INTERACTIONS; REUSABLE CATALYSTS; CO2; METHANATION; CROSS-COUPLINGS; NET TOPOLOGY; MOF;
D O I
10.1016/j.jre.2020.01.012
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In recent years, rare earth metal-organic frameworks (RE-MOFs) have attracted increasing attention because of abundant coordination behaviors, adjustable channels and stable networks. The various electron structures of rare earth ions contribute to the catalytic applications of RE-MOFs and their derivates. In this review, we systematically summarize the research progress that using RE-MOFs and their derivates as catalysts for organic reaction, photocatalytic reaction, and CO oxidation reaction. The major parts include synthetic strategies and catalytic applications of the RE-MOFs. Finally, impressive achievements of RE-MOF catalysts are emerging and a prospect is provided for the development of RE- MOF catalysts at the end of the review. (C) 2020 Published by Elsevier B.V. on behalf of Chinese Society of Rare Earths.
引用
收藏
页码:801 / 818
页数:18
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