Fabrication of Conducting Polyaniline-Coated Halloysite Coaxial Structure Nanocomposites via In Situ Oxidative Graft Polymerization

被引：10
|
作者：
Liu, Yushan [1 ]
Liu, Yongzhao [1 ]
Jiang, Xiaoqing [1 ]
Liu, Tiezhu [1 ]
Yan, Xiaoshe [1 ]
Fan, Yafei [1 ]
Cai, Qiang [2 ,3 ]
Zhang, Jianmin [1 ]
Zhang, Liuxue [4 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Henan Province, Peoples R China
[2] Tsinghua Univ, Minist Educ, Key Lab Adv Mat, Beijing 100084, Peoples R China
[3] Tsinghua Univ, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
[4] Zhongyuan Univ Technol, Coll Mat & Chem Engn, Zhengzhou 450006, Henan Province, Peoples R China
来源：
POLYMER COMPOSITES | 2015年 / 36卷 / 10期
关键词：
COMPOSITE-PARTICLES; CLAY NANOTUBES; CORE-SHELL; ADSORPTION; PRECONCENTRATION; POLYPYRROLE; ANILINE;
D O I：
10.1002/pc.22837
中图分类号：
TB33 [复合材料];
学科分类号：
摘要：
The preparation of conducting g-aminopropyltriethoxysilane halloysite (APHNTs)/polyaniline (PANI) coaxial tubular nanocomposite was conducted via in situ oxidative polymerization after the surface modification of the halloysite nanotubes' (HNTs) surface with gamma-aminopropyltriethoxysilane (gamma-APTES) as modifier and aniline as monomer in the presence of hydrochloric acid (HCl). The products were characterized by Fourier transform infrared spectroscopy analysis, X-ray diffraction, and thermogravimetric analysis. The surface coatings of the gamma-APHNTs and the gamma-APHNTs/PANI hybrids were characterized with X-ray photoelectron spectroscopy. The morphology of gamma-APHNTs/PANI nanocomposites were examined by scanning electron microscopy and transmission electron microscopy. The electrical conductivities of the gamma-APHNTs/PANI were measured using SDY-4 Four-Point Probe Meter. The results showed that the concentration of HCl had no effect on the morphologies and the electrical conductivities of the gamma-APHNTs/PANI nanocomposites increased with more HCl added. (C) 2014 Society of Plastics Engineers
引用
下载
收藏
页码：1759 / 1766
页数：8
相关论文
共 50 条
  • [1] Polyaniline-coated halloysite nanotubes via in-situ chemical polymerization
    Zhang, Long
    Wang, Tingmei
    Liu, Peng
    APPLIED SURFACE SCIENCE, 2008, 255 (05) : 2091 - 2097
  • [2] Conducting polyaniline-coated nano silica by in situ chemical oxidative grafting polymerization
    Lei, Xiping
    Su, Zhixing
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2007, 18 (06) : 472 - 476
  • [3] Preparation of conducting halloysite/polyaniline coaxial tubular nanocomposites in the presence of decorating halloysite as in situ dopant
    Sun, Xun
    Long, Yu
    Wang, Peng
    Sun, Jian
    Ma, Jiantai
    REACTIVE & FUNCTIONAL POLYMERS, 2012, 72 (05): : 323 - 328
  • [4] MECHANICAL AND ELECTRICAL PROPERTIES OF ELECTRICALLY CONDUCTIVE NANOCOMPOSITES OF EPOXY/POLYANILINE-COATED HALLOYSITE NANOTUBES
    Razak, S. I. A.
    Muhamad, I. I.
    Sharif, N. F. A.
    Nayan, N. H. M.
    Rahmat, A. R.
    Yahya, M. Y.
    DIGEST JOURNAL OF NANOMATERIALS AND BIOSTRUCTURES, 2015, 10 (02) : 377 - 384
  • [5] Fabrication of polyaniline-coated halloysite nanotubes by in situ chemical polymerization as a solid-phase microextraction coating for the analysis of volatile organic compounds in aqueous solutions
    Abolghasemi, Mir Mahdi
    Arsalani, Naser
    Yousefi, Vahid
    Arsalani, Mahmood
    Piryaei, Marzieh
    JOURNAL OF SEPARATION SCIENCE, 2016, 39 (05) : 956 - 963
  • [6] Synthesis and characterization of conducting polyaniline-coated cadmium sulphide nanocomposites in reverse microemulsion
    Khiew, PS
    Huang, NM
    Radiman, S
    Ahmad, MS
    MATERIALS LETTERS, 2004, 58 (3-4) : 516 - 521
  • [7] Fabrication of Conductive Polyaniline Nanocomposites Based on Silica Nanoparticles via In-Situ Chemical Oxidative Polymerization Technique
    Babazadeh, Mirzaagha
    Zalloi, Fatemeh
    Olad, Ali
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (01) : 86 - 91
  • [8] FLAME-RETARDANCY OF POLYANILINE-COATED CONDUCTIVE PAPER COMPOSITES PREPARED VIA IN SITU CHEMICAL POLYMERIZATION PROCESS
    Wu, Xianna
    Qian, Xueren
    An, Xianhui
    PROCEEDING OF THE 4TH INTERNATIONAL CONFERENCE ON PULPING, PAPERMAKING AND BIOTECHNOLOGY (ICPPB '12), VOLS. I AND II, 2012, : 520 - 525
  • [9] Conductive Nanocomposites Based on Cellulose Nanofibrils Coated with Polyaniline-DBSA Via In Situ Polymerization
    Silva, Michael J.
    Sanches, Alex O.
    Malmonge, Luiz F.
    Medeiros, Eliton S.
    Rosa, Morsyleide F.
    McMahan, Colleen M.
    Malmonge, Jose A.
    MACROMOLECULAR SYMPOSIA, 2012, 319 (01) : 196 - 202
  • [10] Synthesis and Characterization of CTAB-Intercalated Graphene/Polyaniline Nanocomposites via In Situ Oxidative Polymerization
    Liu, Tiezhu
    Liu, Yushan
    Yan, Xiaoshe
    Fan, Yafei
    Wang, Pan
    Cai, Qiang
    Zhang, Jianmin
    POLYMER COMPOSITES, 2015, 36 (10) : 1767 - 1774
12345