[4-(2-Aminoethyl)morpholine-κ2 N,N′]aqua(oxalato-κ2 O,O′) copper(II) monohydrate

被引：0
|
作者：
Kocwin-Gielzak, K [1 ]
Marciniak, B [1 ]
机构：
[1] Jan Dlugosz Univ, Inst Chem & Environm Protect, PL-42200 Czestochowa, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536805042091
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [Cu(C2O4)(C6H14N2O)(H2O)] center dot H2O, includes a CuN2O3 coordination polyhedron in the shape of a slightly distorted square pyramid with bidentate morpholine and oxalate ligands. Copper(II) is coordinated by 4-(2-aminoethyl) morpholine (etMorph) N atoms, with Cu-N distances of 2.050 (3) and 1.985 (3) angstrom, and two carboxylate O atoms from the oxalate ligand, with Cu-O distances of 1.955 (2) and 1.965 ( 2) angstrom; both ligands are located in the basal plane, whereas a water molecule is apically positioned [Cu-O = 2.251 (3) angstrom]. The crystal packing is dominated by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds.
引用
收藏
页码：M155 / M157
页数：3
相关论文
共 50 条
  • [1] [4-(2-Aminoethyl)morpholine-κ2N,N']dibromido-cadmium(II): synthesis, crystal structure and Hirshfeld surface analysis
    Chidambaranathan, B.
    Sivaraj, S.
    Vijayamathubalan, P.
    Rajasekar, S. Abraham
    Selvakumar, S.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2024, 80 : 271 - +
  • [2] (Oxalato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)-palladium(II) monohydrate
    Odoko, M
    Wang, Y
    Okabe, N
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : M1825 - M1827
  • [3] μ-oxalato-κ4O,O′:O",O′"-bis[chloro(1,10-phenanthroline-κ2N,N′)copper(II)]
    Wang, Min
    Hu, Bo
    Deng, Xiao-Tao
    Wang, Cheng-Gang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : m710 - m711
  • [4] Bis[N-(2-aminoethyl)morpholine]copper(II)bis(tetrafluoroborate)
    Sander, O
    Tuczek, F
    Näther, C
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M824 - M825
  • [5] NICKEL(II) AND COPPER(II) COMPLEXES OF N-(2-AMINOETHYL)- AND N-(2-(2-AMINOETHYL)AMINOETHYL)-SALICYLAMIDE
    NONOYAMA, M
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1974, 4 (04): : 365 - 372
  • [6] Aqua(oxalato-κ2O,O′)oxo(1,10-phenanthroline-κ2N,N′)vanadium(IV)
    Fu, YL
    Ren, JL
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1584 - M1586
  • [7] trans-bis(2-aminoanilinium-κN2)bis(oxalato-κ2O,O′)copper(II)
    Keene, TD
    Hursthouse, MB
    Price, DJ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M1131 - M1133
  • [8] Aqua(di-2-pyridylamine-κ2N,N′)(malonato-κ2O,O′)copper(II) monohydrate
    Youngme, Sujittra
    Phatchimkun, Jaturong
    Chaichit, Narongsak
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2006, 62 : M602 - M603
  • [9] catena-Poly[[[2-(2-chlorophenoxy)-N′-(2-oxidobenzylidene-κO)acetohydrazidato-κ2N′,O]copper(II)]-μ-morpholine-κ2N:O]
    Wang, Min
    Lian, Zhao-Xun
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2013, 69 : 594 - +
  • [10] (Morpholine-κN)(salicylaldehyde 4-nitrobenzoyl-hydrazonato-κ3O,N,O′)copper(II)
    Yuan, LH
    Wu, QJ
    Liu, SX
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1310 - M1312
12345