Synthesis of new chromogenic calix[4]crowns and molecular recognition of alkylamines

被引：56
|
作者：
Zheng, QY [1 ]
Chen, CF [1 ]
Huang, ZT [1 ]
机构：
[1] CHINESE ACAD SCI,INST CHEM,BEIJING 100080,PEOPLES R CHINA
来源：
TETRAHEDRON | 1997年 / 53卷 / 30期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1016/S0040-4020(97)00653-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new type of calix[4]crown containing ester group 3 has been synthesized and selectively nitrated to give 4 or ipso-nitrated to give 6. By nitration a novel calixcrown 5 containing a quinone segment was obtained. These nitrated calixcrowns have been used as chromogenic hosts for complexing alkylamines and the factors affecting recognition are discussed. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：10345 / 10356
页数：12
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