Polymerization of 4-nitrophenyl acrylate under microwave heating conditions

被引：13
|
作者：
Dikusar, MA
Kubrakova, IV
Chinarev, AA
Bovin, NV
机构：
[1] Russian Acad Sci, Shemyakin Ovchinnikov Inst Bioorgan Chem, Moscow 117997, Russia
[2] VI Vernadskii Inst Geochem & Analyt Chem, Moscow 117975, Russia
来源：
RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY | 2001年 / 27卷 / 06期
关键词：
microwave heating; multivalent glycoconjugates; poly(4-nitrophenyl actylate); radical polymerization;
D O I：
10.1023/A:1012949005183
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The 2,2'-azodiisobutyronitrile-induced radical polymerization in solution of 4-nitrophenyl acrylate was performed under microwave heating at a frequency of 2.45 GHz. This approach allows the control of the molecular weight of poly(4-nitrophenyl acrylate) used in the synthesis of multivalent glycoconjugates. It was found that the polymerization of 4-nitrophenyl acrylate under microwave irradiation results in products with a narrower molecular mass distribution than at conventional heating.
引用
收藏
页码：408 / 412
页数：5
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