Epoxidation and oxidation of alcohols -: A new procedure using the methylalumoxane/tert-butyl hydroperoxide system

被引：9
|
作者：
Palombi, L
Scettri, A
Barrella, A
Proto, A
机构：
[1] Univ La Sapienza, Dipartimento Chim, Ctr CNR Studio Chim Sostanze Organ Nat, I-00185 Rome, Italy
[2] Univ Salerno, Dipartimento Chim, I-84081 Salerno, Italy
来源：
GREEN CHEMISTRY | 1999年 / 1卷 / 01期
关键词：
D O I：
10.1039/a809768b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Here reported are the first applications of methylalumoxane, an oligomeric compound of formula (MeAlO)(n), as a catalyst for the epoxidation of allylic alcohols and the oxidation of benzylic, aliphatic (cyclic and linear) alcohols into the corresponding carbonyl compounds.
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页码：27 / 29
页数：3
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