Cu-Catalyzed Photoredox Chlorosulfonation of Alkenes and Alkynes

被引:62
|
作者
Alkan-Zambada, Murat [1 ]
Huo, Xile [1 ]
机构
[1] Ecole Polytech Fed Lausanne, ISIC LSCI, Inst Chem Sci & Engn, Lab Inorgan Synth & Catalysis, BCH 3305, CH-1015 Lausanne, Switzerland
来源
JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 84卷 / 07期
基金
瑞士国家科学基金会;
关键词
TRANSFER RADICAL-ADDITION; SULFONYLATION; SULFONES;
D O I
10.1021/acs.joc.9b00238
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Visible-light photoredox chlorosulfonation of alkenes and alkynes is achieved using a Cu photocatalyst. The reactions occur under mild conditions, have broad scope, and have high functional group tolerance.
引用
收藏
页码:4525 / 4533
页数:9
相关论文
共 50 条
  • [1] Cu-Catalyzed Transformation of Alkynes and Alkenes with Azide and Dimethyl Sulfoxide Reagents
    Shen, Tao
    Huang, Xiaoqiang
    Liang, Yu-Feng
    Jiao, Ning
    [J]. ORGANIC LETTERS, 2015, 17 (24) : 6186 - 6189
  • [2] Recent advances in Cu-catalyzed transformations of internal alkynes to alkenes and heterocycles
    Rasool, Javeed Ur
    Ali, Asif
    Ahmad, Qazi Naveed
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (47) : 10259 - 10287
  • [3] Cu-Catalyzed Aminodifluoroalkylation of Alkynes and α-Bromodifluoroacetamides
    Lv, Yunhe
    Pu, Weiya
    Chen, Qan
    Wang, Qingqing
    Niu, Jiejie
    Zhang, Qian
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (15): : 8282 - 8289
  • [4] Cu-catalyzed intramolecular hydroarylation of alkynes
    Wang, Yun-Long
    Zhang, Wen-Man
    Dai, Jian-Jun
    Feng, Yi-Si
    Xu, Hua-Jian
    [J]. RSC ADVANCES, 2014, 4 (106): : 61706 - 61710
  • [5] Cu-Catalyzed Cascades to Carbocycles: Union of Diaryliodonium Salts with Alkenes or Alkynes Exploiting Remote Carbocations
    Zhang, Fengzhi
    Das, Shoubhik
    Walkinshaw, Andrew J.
    Casitas, Alicia
    Taylor, Michael
    Suero, Marcos G.
    Gaunt, Matthew J.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (25) : 8851 - 8854
  • [6] Cu-catalyzed hydrofluoroacetylation of alkynes or alkynyl carboxylic acids leading highly stereoselectively to fluoroacetylated alkenes
    Ke, Miaolin
    Feng, Qiang
    Yang, Kai
    Song, Qiuling
    [J]. ORGANIC CHEMISTRY FRONTIERS, 2016, 3 (02): : 150 - 155
  • [7] Enantioselective Cu-Catalyzed Functionalizations of Unactivated Alkenes
    Soradova, Zuzana
    Sebesta, Radovan
    [J]. CHEMCATCHEM, 2016, 8 (16) : 2581 - 2588
  • [8] Cu-Catalyzed Asymmetric Alkylamination of Unactivated Alkenes
    Wang, Zixuan
    Li, Bijie
    [J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2021, 41 (03) : 1257 - 1258
  • [9] Stereoselective Photoredox-Catalyzed Chlorotrifluoromethylation of Alkynes: Synthesis of Tetrasubstituted Alkenes
    Han, Hong Sik
    Lee, Young Jin
    Jung, Young-Sik
    Han, Soo Bong
    [J]. ORGANIC LETTERS, 2017, 19 (08) : 1962 - 1965
  • [10] Photoredox-Catalyzed Stereoselective Conversion of Alkynes into Tetrasubstituted Trifluoromethylated Alkenes
    Tomita, Ren
    Koike, Takashi
    Akita, Munetaka
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (44) : 12923 - 12927