Efficient microwave-promoted synthesis of glucuronic and galacturonic acid derivatives using sulfuric acid impregnated on silica

被引：10

作者：

Richel, Aurore ^{[1
]}

Nicks, Francois ^{[1
,2
]}

Laurent, Pascal ^{[1
,2
]}

Wathelet, Bernard ^{[1
]}

Wathelet, Jean-Paul ^{[2
]}

Paquot, Michel ^{[1
]}

机构：

[1] Univ Liege Gembloux Agrobio Tech, Unit Biol & Ind Chem, B-5030 Gembloux, Belgium

[2] Univ Liege Gembloux Agrobio Tech, Unit Gen & Organ Chem, B-5030 Gembloux, Belgium

来源：

GREEN CHEMISTRY LETTERS AND REVIEWS | 2012年 / 5卷 / 02期

关键词：

microwave chemistry; carbohydrates; heterogeneous catalysis; silica; supported catalysts; URONIC-ACIDS; METHYL; GLYCOFURANOSIDES; MIXTURES;

D O I：

10.1080/17518253.2011.607852

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Monomode microwave-assisted syntheses of D-glucuronic and D-galacturonic acid derivatives are reported in the presence of a solid acid catalyst, consisting of sulfuric acid loaded onto silica. This approach affords a variety of surface-active monoglycosylated glucofuranosidurono-6,3-lactones and disubstituted galacturonic adducts in excellent yields in less than 10 min at 85 degrees C. This study illustrates the application of microwave heating mode, in combination with a cost-effective solid catalyst, as an efficient, selective, and eco-friendly methodology in carbohydrate chemistry. [GRAPHICS] .

引用

页码：179 / 186

页数：8

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