Improving the cycling performance of silver-zinc battery by introducing PEG-200 as electrolyte additive

被引:26
|
作者
Lyu, Luyang [1 ]
Gao, Yunfei [1 ]
Wang, Yingming [1 ]
Xiao, Li [1 ]
Lu, Juntao [1 ]
Zhuang, Lin [1 ]
机构
[1] Wuhan Univ, Coll Chem & Mol Sci, Hubei Key Lab Electrochem Power Sources, Wuhan 430072, Hubei, Peoples R China
基金
中国国家自然科学基金;
关键词
Zinc-silver batteries; PEG-200; Zinc dendrites; Cycling performance; Electrolyte additive; ELECTROCHEMICAL-BEHAVIOR; POLYETHYLENE-GLYCOL; DENDRITIC GROWTH; AIR BATTERIES; CORROSION; OXIDE; ELECTRODEPOSITION; ANODES; SURFACE; POWDER;
D O I
10.1016/j.cplett.2019.02.032
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The growth of zinc dendrites during cycling has constrained the development of the silver-zinc batteries. Herein, we focus on the practical application of polyethylene glycol with molecular weight of 200 as an electrolyte additive to the silver-zinc batteries. The cycleability of the batteries was significantly improved by introducing proper amount PEG-200 into the alkaline electrolyte. Further study shows that adding PEG-200 as electrolyte additive can effectively maintain the structure of the zinc electrode, and clearly inhibit the growth of zinc dendrites. At the same time, silver electrodes are not sensitive to the PEG-200 addition.
引用
收藏
页码:102 / 110
页数:9
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