Regiospecific ligand oxygenation in iron complexes of a carboxylate-containing ligand mediated by a proposed Fev-oxo species

被引：48

作者：

Nielsen, A ^{[1
]}

Larsen, FB ^{[1
]}

Bond, AD ^{[1
]}

McKenzie, CJ ^{[1
]}

机构：

[1] Univ So Denmark, Dept Chem, DK-5230 Odense M, Denmark

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 10期

关键词：

hydroxylation; iron; N ligands; N oxides; peroxides;

D O I：

10.1002/anie.200502656

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Mimicked: Through biomimetic iron activation of peroxides (H2O2 or tBuOOH), the shown N4O ligands in their iron(III) complexes can be oxygenated selectively at either an aromatic carbon atom or an aliphatic nitrogen atom. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1602 / 1606

页数：5

共 10 条

[1] SYNTHESIS AND CHARACTERIZATION OF TWO NOVEL TRINUCLEAR OXO-CENTERED, OF CHROMIUM AND IRON COMPLEXES CONTAINING UNSATURATED CARBOXYLATE BRIDGING LIGAND
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[3] Roles of carboxylate donors in O-O bond scission of peroxodi-iron(III) to high-spin oxodi-iron(IV) with a new carboxylate-containing dinucleating ligand
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[4] Synthesis and characterization of iron(III) complexes of a new ligand containing a potentially bridging carboxylate; structural characterization of a helical tetranuclear iron complex
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[6] Intramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron Complexes
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[7] Chemical basis for high activity in oxygenation of cyclohexane catalyzed by dinuclear iron(III) complexes with ethereal oxygen containing ligand and hydrogen peroxide system
Departments of Chemistry, Faculty of Science, Yamagata University, Yamagata 990, Japan
不详
不详
Z. Naturforsch. Sect. B J. Chem. Sci., 6 (719-727):
[8] Chemical basis for high activity in oxygenation of cyclohexane catalyzed by dinuclear iron(III) complexes with ethereal oxygen containing ligand and hydrogen peroxide system
Ito, S
Okuno, T
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Ohba, S
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[9] Singly anti-anti carboxylate-bridged zig-zag chain complexes from a carboxylate-containing tridentate Schiff base ligand and M(hfac)2 [M = MnII, NiII, and CuII]:: Synthesis, crystal structure, and magnetic properties
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Domínguez-Vera, JM
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EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 1999, (03) : 441 - 445
[10] TETRANUCLEAR IRON-OXO COMPLEXES - SYNTHESIS, STRUCTURE, AND PROPERTIES OF SPECIES CONTAINING THE NONPLANAR (FE4O2)8+ CORE AND 7 BRIDGING CARBOXYLATE LIGANDS
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) : 6318 - 6326

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