Synthesis, Structure and Property of a New Diphosphopentamolybdates [C7H7N2]2[H2P2Mo5O23]0.5•3.5H2O

被引：4

作者：

Harchani, Ali ^{[1
]}

Haddad, Amor ^{[1
]}

机构：

[1] Fac Sci Monastir, Dept Chim, LMC, Monastir, Tunisia

来源：

JOURNAL OF CLUSTER SCIENCE | 2015年 / 26卷 / 05期

关键词：

Diphosphopentamolybdate; Synthesis; Crystal structure; Characterizations; CRYSTAL-STRUCTURE; POLYOXOMETALATE; POLYANION;

D O I：

10.1007/s10876-015-0864-z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new diphosphopentamolybdate (VI) [C7H7N2](2)[H2P2Mo5O23](0.5)center dot 3.5H(2)O (1) has been synthesized and structurally characterized by single crystal X-ray diffraction, scanning electron microscopy, IR, thermal stability analysis, cyclic voltammetry analyzes and UV-Vis. The compound 1 crystallizes in the monoclinic, space group C2/c, a = 23.267 (3) , b = 16.759 (2) , c = 13.756 (3) , beta = 110.57 (1)A degrees , Z = 8. The crystal structure of 1 also contains the isolated polyanion units [H2P2Mo5O23](4-) around the protonated 3-Aminbenzonitrile ions and lattice water. The hydrogen bond hold the components together into a three-dimensional network and make the crystal structure of the compound more stable.

引用

页码：1645 / 1653

页数：9

共 50 条

[1] Synthesis, Structure and Property of a New Diphosphopentamolybdates [C7H7N2]2[H2P2Mo5O23]0.5·3.5H2O
Ali Harchani
Amor Haddad
Journal of Cluster Science, 2015, 26 : 1645 - 1653
[2] Synthesis, characterization, Hirshfeld surface and theoretical properties of (C7H10N)4[H2P2Mo5O23] • H2O
Harchani, Ali
Kucerakova, Monika
Dusek, Michal
Haddad, Amor
JOURNAL OF CHEMICAL SCIENCES, 2017, 129 (10) : 1539 - 1547
[3] Synthesis, structure and property of a new inorganic-organic hybrid compound [Cu(phen)2][Cu(phen)H2O]2[Mo5P2O23]•3.5H2O
Wu, Lizhou
Ma, Huiyuan
Han, Zhangang
Li, Chunxiang
SOLID STATE SCIENCES, 2009, 11 (01) : 43 - 48
[4] Synthesis and crystal structure of KBi(C6H4O7) • 3.5H2O
Antsyshkina, A. S.
Sadikov, G. G.
Kuvshinova, T. B.
Skorikov, V. M.
Sergienko, V. S.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (03) : 374 - 385
[5] Synthesis and crystal structure of KBi(C6H4O 7) • 3.5H2O
Antsyshkina A.S.
Sadikov G.G.
Kuvshinova T.B.
Skorikov V.M.
Sergienko V.S.
Russ. J. Inorg. Chem., 2006, 3 (374-385): : 374 - 385
[6] Hydrothermal synthesis, crystal structure and properties of supermolecular compound (bipyH2)2(H2P2Mo5O23) • H2O
Zhao, SL
Zhang, HH
Huang, CC
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2002, 23 (04): : 521 - 525
[7] Hydrothermal synthesis, crystal structure and properties of supermolecular compound (bipyH2)2 (H2P2Mo5O23 ·H2O)
Zhao, Shi-Long
Zhang, Han-Hui
Huang, Chang-Cang
Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 2002, 23 (04):
[8] Physico-Chemical Characterization of a New Hybrid Material (NH4)2(C6H18N2)[H2P2Mo5O23]<middle dot>H2O: Quantum Chemical and Comparative Studies with Homologous (C6H18N2)2[H2P2Mo5O23]<middle dot>H2O
Hichri, Amal
Roisnel, Thierry
Abid, Sonia
CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY, 2024, 7 (05): : 2419 - 2431
[9] Synthesis and crystal structure of the hydrated magnesium diphosphate Mg2P2O7•3.5H2O and its high temperature variant Mg2P2O7•H2O
Kongshaug, KO
Fjellvåg, H
Lillerud, KP
SOLID STATE SCIENCES, 2000, 2 (02) : 205 - 214
[10] Hydrothermal synthesis and structure of [(C4N2H12)3][P2Mo5O23].H2O and [(C3N2H12)3][P2Mo5O23].4H2O
Ganesan, SV
Natarajan, S
JOURNAL OF CHEMICAL SCIENCES, 2005, 117 (03) : 219 - 226

← 1 2 3 4 5 →