Cu2ZnSnS4 thin films by sulfurization in melted sulfur

被引：3

作者：

Bashkirov, S. A. ^{[1
]}

Hekkel, U. S. ^{[1
]}

Tivanov, M. S. ^{[2
]}

Saad, A. M. ^{[3
]}

机构：

[1] NAS Belarus, Sci Pract Mat Res Ctr, Minsk 220072, BELARUS

[2] Belarusian State Univ, Nezavisimosti Av 4, Minsk 220030, BELARUS

[3] Al Balqa Appl Univ, POB 4545, Amman 11953, Jordan

来源：

MATERIALS LETTERS | 2018年 / 220卷

关键词：

Cu2ZnSnS4; CZTS; Thin films; Electrochemical deposition; Sulfurization; Liquid-based process;

D O I：

10.1016/j.matlet.2018.03.035

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Cu2ZnSnS4 (CZTS) thin films were synthesized by sulfurization of subsequently electrochemically deposited Cu/Sn/Zn metal precursors on Mo foil substrates in melted sulfur on air at the temperature of 440 degrees C close to the sulfur boiling point for 1 h. The films contain only CZTS phase with lattice parameters a = 5.422 +/- 0.002 angstrom and c = 10.811 +/- 0.006 angstrom and components at. % ratio: Cu/(Sn + Zn) = 1.05, Zn/Sn = 1.22, (Cu + Sn + Zn)/S = 0.93. The film surface is densely packed without cracks or pinholes. The obtained results show the practical ability to obtain CZTS thin films by a novel technically simple and low-cost liquid-based process. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：126 / 128

页数：3

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