Experimental investigations for recycling of silicon and glass from waste photovoltaic modules

被引:217
|
作者
Kang, Sukmin [1 ,2 ]
Yoo, Sungyeol [1 ]
Lee, Jina [1 ]
Boo, Bonghyun [2 ]
Ryu, Hojin [1 ]
机构
[1] Korea Res Inst Chem Technol, Energy Mat Res Ctr, Taejon 305600, South Korea
[2] Chungnam Natl Univ, Dept Chem, Taejon 305764, South Korea
关键词
Photovoltaic module; Ethylene vinyl acetate; Etching solution; Silicon; Recycling; SOLAR; FEEDSTOCK;
D O I
10.1016/j.renene.2012.04.030
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This paper reports a new procedure for the recovery of resources from waste photovoltaic modules. The tempered glass was recovered using organic solvents. The metal impurities were removed by applying a chemical etching solution on the surface of the PV cell. We offer a much more efficient approach for recycling PV cells than the conventional method. The highest yield of silicon recovered was 86% when the PV cell was placed in the chemical etching solution for 20 min, along with the surfactant, which accounted for 20% of the total solution's weight at room temperature. This investigation showed that a high yield of pure silicon with purity of 99.999% could be obtained. The recovered pure silicon from waste PV modules would be contributed to the solution of several problems such as the supply of silicon, manufacturing costs, and end-of-life management of PV modules. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:152 / 159
页数:8
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