The first reductive cyclization by lithium aluminum hydride: stereospecific reductive cyclization of 1-(methoxycarbonylmethyl)imidazolidin-4-ones

被引：2
|
作者：
Chen, FL [1 ]
Sung, KS [1 ]
机构：
[1] Natl Cheng Kung Univ, Dept Chem, Tainan 70101, Taiwan
来源：
TETRAHEDRON LETTERS | 2006年 / 47卷 / 17期
关键词：
reductive cyclization; lithium aluminum hydride; stereospecific reaction;
D O I：
10.1016/j.tetlet.2006.02.121
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The first LiAlH4-driven reductive cyclization of the bifunctional 1-(methoxycarbonylmethyl)imidazolidin-4-ones, (-)-1a-c or (+)-1a-c, stereospecifically generated the corresponding 1.6-diaza-4-oxa-bicyclo[3.2.1]octanes, (-)-3a-c or (+)-3a-c with a novel bicyclic system. (c) 2006 Elsevier Ltd. All rights reserved.
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页码：2899 / 2903
页数：5
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